000135317 001__ 135317
000135317 005__ 20250923084419.0
000135317 0247_ $$2doi$$a10.1002/chem.202400881
000135317 0248_ $$2sideral$$a138583
000135317 037__ $$aART-2024-138583
000135317 041__ $$aeng
000135317 100__ $$aDemonti, Luca
000135317 245__ $$aSynthesis and Lewis Acid Properties of Neutral Silver(III) Adducts Containing the Ag<sup>III</sup>(CF<sub>3</sub>)<sub>3</sub> Moiety
000135317 260__ $$c2024
000135317 5060_ $$aAccess copy available to the general public$$fUnrestricted
000135317 5203_ $$aThe acetonitrile AgIII complex [AgIII(CF3)3(NCCH3)] (2) has been reported independently by Eujen and Naumann in the last century, albeit with intriguing NMR discrepancy. In their reports, 2 was claimed to be obtained starting from either [AgIII(CF3)3Cl]− (3⋅Cl) or [AgIII(CF3)4]− (1) via halide abstraction using AgNO3 or acidic treatment, resp. These two synthetic routes are herein reinvestigated. The feasibility of Naumann's method is demonstrated, thus providing 2 yet accompanied by its s‐triazinyl derivative [AgIII(CF3)3(C6H9N3)] (2’). The formation of 2’ is unprecedented and was thereby investigated. Both 2 and 2’ were isolated in pure fashion and fully characterized. In turn, halide extraction from 3⋅Cl leads to the AgIII‐ONO2 anion 5 instead of 2, as evidenced by NMR spectroscopy, EA and Sc‐XRD.
000135317 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E17-23R$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-122869NB-I00
000135317 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000135317 590__ $$a3.7$$b2024
000135317 592__ $$a0.981$$b2024
000135317 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b95 / 239 = 0.397$$c2024$$dQ2$$eT2
000135317 593__ $$aChemistry (miscellaneous)$$c2024$$dQ1
000135317 593__ $$aOrganic Chemistry$$c2024$$dQ1
000135317 593__ $$aCatalysis$$c2024$$dQ2
000135317 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000135317 700__ $$0(orcid)0000-0002-0204-7713$$aJoven-Sancho, Daniel
000135317 700__ $$aSaffon-Merceron, Nathalie
000135317 700__ $$0(orcid)0000-0002-2492-625X$$aBaya, Miguel$$uUniversidad de Zaragoza
000135317 700__ $$aNebra, Noel
000135317 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000135317 773__ $$g(2024), e202400881 [8 pp.]$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000135317 8564_ $$s4381538$$uhttps://zaguan.unizar.es/record/135317/files/texto_completo.pdf$$yVersión publicada
000135317 8564_ $$s2796855$$uhttps://zaguan.unizar.es/record/135317/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000135317 909CO $$ooai:zaguan.unizar.es:135317$$particulos$$pdriver
000135317 951__ $$a2025-09-22-14:34:38
000135317 980__ $$aARTICLE