000135323 001__ 135323
000135323 005__ 20240711085513.0
000135323 0247_ $$2doi$$a10.1016/j.sab.2024.106941
000135323 0248_ $$2sideral$$a138581
000135323 037__ $$aART-2024-138581
000135323 041__ $$aeng
000135323 100__ $$0(orcid)0000-0001-5382-0561$$aBolea, Eduardo$$uUniversidad de Zaragoza
000135323 245__ $$aSingle particle inductively coupled plasma mass spectrometry metrology: Revisiting the transport efficiency paradigm
000135323 260__ $$c2024
000135323 5060_ $$aAccess copy available to the general public$$fUnrestricted
000135323 5203_ $$aTransport efficiency has become a critical parameter in single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) since it is involved in the calibrations to determine different measurands (element mass per particle, particle size and particle number concentration). Specific methods for its determination based on the use of particle standards have been developed and widely applied (particle frequency and particle size methods). A refined indirect method not relying on particle standards is also available (dynamic mass flow method). A number of discrepancies on the accuracy of these methods and their adequacy have become evident, making a revision of the topic pertinent. In fact, the application of the particle frequency and particle size methods determine the transport efficiencies corresponding to the particles or the dissolved element respectively, whereas the solvent transport efficiency is actually measured by the dynamic mass flow method. The use of each of these methods requires assuming different conditions that must be considered. These conditions, together with the sources of bias associated to each method are critically discussed to provide a holistic and harmonized view of transport efficiency in the context of SP-ICP-MS metrology
000135323 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FEDER/E29-23R$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-123203OB-I00
000135323 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000135323 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000135323 700__ $$0(orcid)0000-0002-4169-0357$$aLaborda, Francisco$$uUniversidad de Zaragoza
000135323 7102_ $$12009$$2750$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cÁrea Química Analítica
000135323 773__ $$g216 (2024), 106941 [7 pp.]$$pSpectrochim. acta, Part B: Atom. spectrosc.$$tSpectrochimica Acta - Part B Atomic Spectroscopy$$x0584-8547
000135323 8564_ $$s822049$$uhttps://zaguan.unizar.es/record/135323/files/texto_completo.pdf$$yVersión publicada
000135323 8564_ $$s2575748$$uhttps://zaguan.unizar.es/record/135323/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000135323 909CO $$ooai:zaguan.unizar.es:135323$$particulos$$pdriver
000135323 951__ $$a2024-07-11-08:52:31
000135323 980__ $$aARTICLE