000136310 001__ 136310
000136310 005__ 20250923084420.0
000136310 0247_ $$2doi$$a10.1002/chem.202401825
000136310 0248_ $$2sideral$$a139261
000136310 037__ $$aART-2024-139261
000136310 041__ $$aeng
000136310 100__ $$0(orcid)0000-0002-5298-8351$$aPérez-Sánchez, Juan Carlos
000136310 245__ $$aThe Potential of Self-Activating Au(I) Complexes in Gold Catalysis
000136310 260__ $$c2024
000136310 5060_ $$aAccess copy available to the general public$$fUnrestricted
000136310 5203_ $$aGold catalysis has emerged as a groundbreaking field in synthetic chemistry, revolutionizing numerous organic transformations. Despite the significant achieved advancements, the mechanistic understanding behind many gold‐catalyzed reactions remains elusive. This Concept article covers the so‐called “self‐activating” Au(I) complexes, sorting out their pivotal role in gold catalysis. We comment on how Au(I) complexes can undergo self‐activation, triggering diverse catalytic transformations without the need for external additives. The most important examples reported so far that underlie the catalytic activity of these species are discussed. This intrinsic reactivity represents a paradigm shift in gold catalysis, offering new avenues for the design of efficient and sustainable catalytic systems. Furthermore, we explore the factors influencing the stability, reactivity, and selectivity of these Au(I) complexes, providing insights into their synthetic utility and potential applications. This area of research not only advances our fundamental understanding of gold catalysis but also paves the way for the development of novel catalytic strategies with broad implications in organic synthesis and the chemical industry.
000136310 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E07-23R$$9info:eu-repo/grantAgreement/ES/MICINN AEI/PID2022-136861NB-I00
000136310 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000136310 590__ $$a3.7$$b2024
000136310 592__ $$a0.981$$b2024
000136310 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b95 / 239 = 0.397$$c2024$$dQ2$$eT2
000136310 593__ $$aChemistry (miscellaneous)$$c2024$$dQ1
000136310 593__ $$aOrganic Chemistry$$c2024$$dQ1
000136310 593__ $$aCatalysis$$c2024$$dQ2
000136310 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000136310 700__ $$0(orcid)0000-0002-5244-9569$$aPérez Herrera, Raquel
000136310 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M. Concepción
000136310 773__ $$g30, 44 (2024), e202401825 [10 pp.]$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000136310 8564_ $$s6772230$$uhttps://zaguan.unizar.es/record/136310/files/texto_completo.pdf$$yVersión publicada
000136310 8564_ $$s3001256$$uhttps://zaguan.unizar.es/record/136310/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000136310 909CO $$ooai:zaguan.unizar.es:136310$$particulos$$pdriver
000136310 951__ $$a2025-09-22-14:35:31
000136310 980__ $$aARTICLE