144702 20260217205523.0 doi 10.1002/cplu.202400162 sideral 139535 ART-2024-139535 eng Batuecas, María Universidad de Zaragoza (orcid)0000-0002-1430-1440 Recent advances on the chemistry of transition metal complexes with monoanionic bidentate silyl ligands 2024 Access copy available to the general public Unrestricted The chemistry of transition-metal (TM) complexes with monoanionic bidentate (κ2-L,Si) silyl ligands has considerably grown in recent years. This work summarizes the advances in the chemistry of TM-(κ2-L,Si) complexes (L=N-heterocycle, phosphine, N-heterocyclic carbene, thioether, ester, silylether or tetrylene). The most common synthetic method has been the oxidative addition of the Si−H bond to the metal center assisted by the coordination of L. The metal silicon bond distances in TM-(κ2-L,Si) complexes are in the range of metal-silyl bond distances. TM-(κ2-L,Si) complexes have proven to be effective catalysts for hydrosilylation and/or hydrogenation of unsaturated molecules among other processes. info:eu-repo/grantAgreement/ES/DGA/E42-23R info:eu-repo/grantAgreement/EC/H2020/101034288/EU/International Fellowship Programme for Talent Attraction to the Campus of International Excellence Campus Iberus/IberusExperience This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 101034288-IberusExperience info:eu-repo/grantAgreement/ES/MICINN/PID2021-126212OB-I00 info:eu-repo/semantics/openAccess by-nc-nd https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es 2.8 2024 CHEMISTRY, MULTIDISCIPLINARY 114 / 239 = 0.477 2024 Q2 T2 0.73 2024 Chemistry (miscellaneous) 2024 Q2 4.4 2024 info:eu-repo/semantics/review info:eu-repo/semantics/publishedVersion Goméz-España, Alejandra Fernández-Álvarez, Francisco J. Universidad de Zaragoza (orcid)0000-0002-0497-1969 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 89, 9 (2024), e202400162 [22 pp.] ChemPlusChem ChemPlusChem 2192-6506 7038443 http://zaguan.unizar.es/record/144702/files/texto_completo.pdf Versión publicada 1897153 http://zaguan.unizar.es/record/144702/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:144702 articulos driver 2026-02-17-20:29:40 ARTICLE