000144795 001__ 144795 000144795 005__ 20260217205601.0 000144795 0247_ $$2doi$$a10.1002/anie.202405666 000144795 0248_ $$2sideral$$a139508 000144795 037__ $$aART-2024-139508 000144795 041__ $$aeng 000144795 100__ $$aWilson, Lucinda R. B. 000144795 245__ $$aStellated cuboctahedron of Fe III 000144795 260__ $$c2024 000144795 5203_ $$aThe solvothermal reaction of FeCl2 ⋅ 4H2O and H4TBC[4] in a basic dmf/EtOH solution affords an [FeIII18] Keplerate conforming to a stellated cuboctahedron. Magnetic and heat capacity measurements reveal spin frustration effects arising from the high symmetry. A crossover between inverse and direct magnetocaloric effects is observed at ~10 K for applied-field changes lower than 3 T. 000144795 536__ $$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-124734OB-C21 000144795 540__ $$9info:eu-repo/semantics/closedAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/ 000144795 590__ $$a17.0$$b2024 000144795 592__ $$a5.55$$b2024 000144795 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b15 / 239 = 0.063$$c2024$$dQ1$$eT1 000144795 593__ $$aChemistry (miscellaneous)$$c2024$$dQ1 000144795 593__ $$aCatalysis$$c2024$$dQ1 000144795 594__ $$a27.6$$b2024 000144795 655_4 $$ainfo:eu-repo/semantics/conferenceObject$$vinfo:eu-repo/semantics/publishedVersion 000144795 700__ $$aCanaj, Angelos B. 000144795 700__ $$aCutler, Daniel J. 000144795 700__ $$aMcCormick McPherson, Laura J. 000144795 700__ $$aColes, Simon J. 000144795 700__ $$aNojiri, Hiroyuki 000144795 700__ $$0(orcid)0000-0002-8028-9064$$aEvangelisti, Marco 000144795 700__ $$aSchnack, Jürgen 000144795 700__ $$aDalgarno, Scott J. 000144795 700__ $$aBrechin, Euan K. 000144795 773__ $$g63, 37 (2024), e202405666 [6 pp.]$$pAngew. Chem. (Int. ed.)$$tAngewandte Chemie (International ed.)$$x1433-7851 000144795 8564_ $$s1124389$$uhttps://zaguan.unizar.es/record/144795/files/texto_completo.pdf$$yVersión publicada 000144795 8564_ $$s2876067$$uhttps://zaguan.unizar.es/record/144795/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000144795 909CO $$ooai:zaguan.unizar.es:144795$$particulos$$pdriver 000144795 951__ $$a2026-02-17-20:44:41 000144795 980__ $$aARTICLE