000145111 001__ 145111
000145111 005__ 20250923084436.0
000145111 0247_ $$2doi$$a10.1016/j.jorganchem.2024.123377
000145111 0248_ $$2sideral$$a139908
000145111 037__ $$aART-2024-139908
000145111 041__ $$aeng
000145111 100__ $$aCored, Jorge
000145111 245__ $$aEnantioselective Friedel-Crafts alkylation of 1,3,5-trimethoxybenzene with trans-ß-nitrostyrenes catalysed by [Cp*Rh{(R)-Prophos}(H2O)][SbF6]2 (Prophos = propane-1,2-diyl-bis(diphenylphosphane)
000145111 260__ $$c2024
000145111 5060_ $$aAccess copy available to the general public$$fUnrestricted
000145111 5203_ $$aThe aqua complex (SRh,RC)-[Cp*Rh{(R)-Prophos}(H2O)][SbF6]2 (Prophos = propane-1,2-diyl-bis(diphenylphosphane) catalyses the asymmetric Friedel-Crafts (FC) alkylation of 1,3,5-trimethoxybenzene with trans-β-nitrostyrenes. Only the monoalkylated adduct was obtained in all cases with enantioselectivities of up to 93/7 e.r. Solution NMR measurements have allowed us to detect and characterise catalytic intermediates such as metal-trans-β-nitrostyrene and metal‑aci-nitro complexes, as well as free aci‑nitro compound. Based on these studies, a Michael-type Friedel-Crafts mechanism is proposed.
000145111 536__ $$9info:eu-repo/grantAgreement/ES/MCIU/CTQ2018-095561-BI00$$9info:eu-repo/grantAgreement/ES/MCIU-AEI-FEDER/PID2021-122406NB-I00$$9info:eu-repo/grantAgreement/ES/DGA/E05-23R
000145111 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000145111 590__ $$a2.4$$b2024
000145111 592__ $$a0.385$$b2024
000145111 591__ $$aCHEMISTRY, ORGANIC$$b21 / 57 = 0.368$$c2024$$dQ2$$eT2
000145111 593__ $$aBiochemistry$$c2024$$dQ3
000145111 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b22 / 42 = 0.524$$c2024$$dQ3$$eT2
000145111 593__ $$aInorganic Chemistry$$c2024$$dQ3
000145111 593__ $$aPhysical and Theoretical Chemistry$$c2024$$dQ3
000145111 593__ $$aOrganic Chemistry$$c2024$$dQ3
000145111 593__ $$aMaterials Chemistry$$c2024$$dQ3
000145111 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000145111 700__ $$aSánchez, Antonio
000145111 700__ $$0(orcid)0000-0002-6160-3046$$aViguri, Fernando$$uUniversidad de Zaragoza
000145111 700__ $$0(orcid)0000-0002-8845-0174$$aRodríguez, Ricardo
000145111 700__ $$0(orcid)0000-0001-9071-563X$$aLamata, Pilar$$uUniversidad de Zaragoza
000145111 700__ $$aCarmona, Daniel
000145111 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000145111 773__ $$g1021 (2024), 123377 [13 pp.]$$pJ. organomet. chem.$$tJournal of Organometallic Chemistry$$x0022-328X
000145111 8564_ $$s1720265$$uhttps://zaguan.unizar.es/record/145111/files/texto_completo.pdf$$yVersión publicada
000145111 8564_ $$s2682437$$uhttps://zaguan.unizar.es/record/145111/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000145111 909CO $$ooai:zaguan.unizar.es:145111$$particulos$$pdriver
000145111 951__ $$a2025-09-22-14:47:03
000145111 980__ $$aARTICLE