000145136 001__ 145136
000145136 005__ 20241003094705.0
000145136 0247_ $$2doi$$a10.1039/c7cp01739a
000145136 0248_ $$2sideral$$a101109
000145136 037__ $$aART-2017-101109
000145136 041__ $$aeng
000145136 100__ $$0(orcid)0000-0002-1220-3708$$aRoyes, J.
000145136 245__ $$aChiral supramolecular organization from a sheet-like achiral gel: A study of chiral photoinduction
000145136 260__ $$c2017
000145136 5060_ $$aAccess copy available to the general public$$fUnrestricted
000145136 5203_ $$aChiral photoinduction in a photoresponsive gel based on an achiral 2D architecture with high geometric anisotropy and low roughness has been investigated. Circularly polarized light (CPL) was used as a chiral source and an azobenzene chromophore was employed as a chiral trigger. The chiral photoinduction was studied by evaluating the preferential excitation of enantiomeric conformers of the azobenzene units. Crystallographic data and density functional theory (DFT) calculations show how chirality is transferred to the achiral azomaterials as a result of the combination of chiral photochemistry and supramolecular interactions. This procedure could be applied to predict and estimate chirality transfer from a chiral physical source to a supramolecular organization using different light-responsive units.
000145136 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2014-55205-P
000145136 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000145136 590__ $$a3.906$$b2017
000145136 591__ $$aPHYSICS, ATOMIC, MOLECULAR & CHEMICAL$$b9 / 36 = 0.25$$c2017$$dQ1$$eT1
000145136 591__ $$aCHEMISTRY, PHYSICAL$$b46 / 144 = 0.319$$c2017$$dQ2$$eT1
000145136 592__ $$a1.686$$b2017
000145136 593__ $$aPhysics and Astronomy (miscellaneous)$$c2017$$dQ1
000145136 593__ $$aPhysical and Theoretical Chemistry$$c2017$$dQ1
000145136 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000145136 700__ $$0(orcid)0000-0001-5823-7965$$aPolo, V.$$uUniversidad de Zaragoza
000145136 700__ $$0(orcid)0000-0001-7636-9187$$aUriel, S.$$uUniversidad de Zaragoza
000145136 700__ $$0(orcid)0000-0002-0922-5615$$aOriol, L.$$uUniversidad de Zaragoza
000145136 700__ $$0(orcid)0000-0001-5556-2172$$aPiñol, M.$$uUniversidad de Zaragoza
000145136 700__ $$0(orcid)0000-0003-1141-5933$$aTejedor, R.M.$$uUniversidad de Zaragoza
000145136 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000145136 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000145136 773__ $$g19, 21 (2017), 13622-13628$$pPhys. chem. chem. phys.$$tPhysical chemistry chemical physics$$x1463-9076
000145136 8564_ $$s873469$$uhttps://zaguan.unizar.es/record/145136/files/texto_completo.pdf$$yPostprint
000145136 8564_ $$s2529477$$uhttps://zaguan.unizar.es/record/145136/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000145136 909CO $$ooai:zaguan.unizar.es:145136$$particulos$$pdriver
000145136 951__ $$a2024-10-03-08:55:32
000145136 980__ $$aARTICLE