000145419 001__ 145419
000145419 005__ 20241024135331.0
000145419 0247_ $$2doi$$a10.1002/chem.202401753
000145419 0248_ $$2sideral$$a140198
000145419 037__ $$aART-2024-140198
000145419 041__ $$aeng
000145419 100__ $$aRuiz-Almoguera, David
000145419 245__ $$aGold Trifluoromethyl Complexes as Efficient Regioselective Catalysts in Alkyne Hydration
000145419 260__ $$c2024
000145419 5060_ $$aAccess copy available to the general public$$fUnrestricted
000145419 5203_ $$aGold(III) complexes containing trifluoromethyl ligands are efficient catalysts in the hydration of alkynes, operating at low catalyst loadings, without additives, using environmentally friendly solvents and at mild conditions (60 °C). Hydration of terminal and internal alkynes provides the corresponding ketones in quantitative yields without special precautions as dry solvents or inert atmospheres. Remarkably, hydration of asymmetric internal alkynes proceeds with moderate to notable regioselectivities, providing mixtures of the two possible isomers with ratios up to 90 : 10.
000145419 536__ $$9info:eu-repo/grantAgreement/ES/AEI/PID2021-126071OB-C22$$9info:eu-repo/grantAgreement/ES/DGA/E17-23R$$9info:eu-repo/grantAgreement/ES/MEC/FPU15-03940$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-122869NB-I00$$9info:eu-repo/grantAgreement/ES/MICINN/RED2022-134074-T$$9info:eu-repo/grantAgreement/ES/MIU/FPU22-02988
000145419 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000145419 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000145419 700__ $$aVentura-Espinosa, David
000145419 700__ $$0(orcid)0000-0003-2260-676X$$aPérez-Bitrián, Alberto
000145419 700__ $$aMartín, Antonio
000145419 700__ $$aMata, José A.
000145419 700__ $$0(orcid)0000-0002-2492-625X$$aBaya, Miguel$$uUniversidad de Zaragoza
000145419 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000145419 773__ $$g2024, 30 (2024), e202401753 [6 pp.]$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000145419 8564_ $$s1977646$$uhttps://zaguan.unizar.es/record/145419/files/texto_completo.pdf$$yVersión publicada
000145419 8564_ $$s2735305$$uhttps://zaguan.unizar.es/record/145419/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000145419 909CO $$ooai:zaguan.unizar.es:145419$$particulos$$pdriver
000145419 951__ $$a2024-10-24-12:12:40
000145419 980__ $$aARTICLE