000145686 001__ 145686
000145686 005__ 20250923084435.0
000145686 0247_ $$2doi$$a10.1002/chem.202403239
000145686 0248_ $$2sideral$$a140616
000145686 037__ $$aART-2024-140616
000145686 041__ $$aeng
000145686 100__ $$aPolo, Alvaro$$uUniversidad de Zaragoza
000145686 245__ $$aChirality at Metal in a Linear [Ag(NHC)2]+ Complex: Stereogenic C-Ag-C Axis, Atropisomerism and Role of p-p Interactions
000145686 260__ $$c2024
000145686 5060_ $$aAccess copy available to the general public$$fUnrestricted
000145686 5203_ $$aChirality at the metal center is a well‐established concept, exemplified by numerous four‐ and six‐coordinated complexes. Here, a pioneering example of linear chirality‐at‐metal is described: [Ag(NHC)2]+ (NHC=N‐heterocyclic carbene). In solution, stabilizing π‐π interactions preserve the chiral information of the solid state. Consequently, a novel class of atropisomers is identified, whose stereogenicity arises from hindered rotation around a C−Ag−C axis, instead of a typical C−C bond.
000145686 536__ $$9info:eu-repo/grantAgreement/ES/MICINN/PID2022-137208NB-I00$$9info:eu-repo/grantAgreement/ES/MCIU-AEI-FEDER/PID2021-122406NB-I00$$9info:eu-repo/grantAgreement/ES/DGA/E42-23R$$9info:eu-repo/grantAgreement/ES/DGA/E05-23R
000145686 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000145686 590__ $$a3.7$$b2024
000145686 592__ $$a0.981$$b2024
000145686 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b95 / 239 = 0.397$$c2024$$dQ2$$eT2
000145686 593__ $$aChemistry (miscellaneous)$$c2024$$dQ1
000145686 593__ $$aOrganic Chemistry$$c2024$$dQ1
000145686 593__ $$aCatalysis$$c2024$$dQ2
000145686 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000145686 700__ $$aGutiérrez Merino, Lara
000145686 700__ $$0(orcid)0000-0002-8845-0174$$aRodríguez, Ricardo
000145686 700__ $$0(orcid)0000-0002-8220-6031$$aSanz Miguel, Pablo J.$$uUniversidad de Zaragoza
000145686 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000145686 773__ $$g30, 64 (2024), e202403239 [4 p.]$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000145686 8564_ $$s2450324$$uhttps://zaguan.unizar.es/record/145686/files/texto_completo.pdf$$yVersión publicada
000145686 8564_ $$s2541427$$uhttps://zaguan.unizar.es/record/145686/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000145686 909CO $$ooai:zaguan.unizar.es:145686$$particulos$$pdriver
000145686 951__ $$a2025-09-22-14:46:04
000145686 980__ $$aARTICLE