000146914 001__ 146914
000146914 005__ 20260112133235.0
000146914 0247_ $$2doi$$a10.1002/smll.202406533
000146914 0248_ $$2sideral$$a140748
000146914 037__ $$aART-2024-140748
000146914 041__ $$aeng
000146914 100__ $$aD'Agosta, Paolo
000146914 245__ $$aUnraveling the Band Structure and Orbital Character of a p-Conjugated 2D Graphdiyne-Based Organometallic Network
000146914 260__ $$c2024
000146914 5060_ $$aAccess copy available to the general public$$fUnrestricted
000146914 5203_ $$aGraphdiyne‐based carbon systems generate intriguing layered sp–sp2 organometallic lattices, characterized by flexible acetylenic groups connecting planar carbon units through metal centers. At their thinnest limit, they can result in 2D organometallic networks exhibiting unique quantum properties and even confining the surface states of the substrate, which is of great importance for fundamental studies. In this work, the on‐surface synthesis of a highly crystalline 2D organometallic network grown on Ag(111) is presented. The electronic structure of this mixed honeycomb‐kagome arrangement – investigated by angle‐resolved photoemission spectroscopy and scanning tunneling spectroscopy – reveals a strong electronic conjugation within the network, leading to the formation of two intense electronic band‐manifolds. In comparison to theoretical density functional theory calculations, it is observed that these bands exhibit a well‐defined orbital character that can be associated with distinct regions of the sp–sp2 monomers. Moreover, it is found that the halogen by‐products resulting from the network formation locally affect the pore‐confined states, causing a significant energy shift. This work contributes to the understanding of the growth and electronic structure of graphdiyne‐like 2D networks, providing insights into the development of novel carbon materials beyond graphene with tailored properties.
000146914 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttps://creativecommons.org/licenses/by/4.0/deed.es
000146914 590__ $$a12.1$$b2024
000146914 592__ $$a3.301$$b2024
000146914 591__ $$aCHEMISTRY, PHYSICAL$$b24 / 185 = 0.13$$c2024$$dQ1$$eT1
000146914 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b42 / 460 = 0.091$$c2024$$dQ1$$eT1
000146914 591__ $$aNANOSCIENCE & NANOTECHNOLOGY$$b17 / 147 = 0.116$$c2024$$dQ1$$eT1
000146914 591__ $$aPHYSICS, CONDENSED MATTER$$b8 / 79 = 0.101$$c2024$$dQ1$$eT1
000146914 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b24 / 239 = 0.1$$c2024$$dQ1$$eT1
000146914 591__ $$aPHYSICS, APPLIED$$b14 / 187 = 0.075$$c2024$$dQ1$$eT1
000146914 593__ $$aBiomaterials$$c2024$$dQ1
000146914 593__ $$aBiotechnology$$c2024$$dQ1
000146914 593__ $$aChemistry (miscellaneous)$$c2024$$dQ1
000146914 593__ $$aNanoscience and Nanotechnology$$c2024$$dQ1
000146914 593__ $$aMaterials Science (miscellaneous)$$c2024$$dQ1
000146914 593__ $$aMedicine (miscellaneous)$$c2024$$dQ1
000146914 593__ $$aEngineering (miscellaneous)$$c2024$$dQ1
000146914 594__ $$a16.1$$b2024
000146914 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000146914 700__ $$aAchilli, Simona
000146914 700__ $$aTumino, Francesco
000146914 700__ $$aOrbelli Biroli, Alessio
000146914 700__ $$aDi Santo, Giovanni
000146914 700__ $$aPetaccia, Luca
000146914 700__ $$aOnida, Giovanni
000146914 700__ $$aLi Bassi, Andrea
000146914 700__ $$0(orcid)0000-0003-2698-2543$$aLobo-Checa, Jorge
000146914 700__ $$aCasari, Carlo S.
000146914 773__ $$g(2024), 2406533 [9 pp.]$$pSmall$$tSmall$$x1613-6810
000146914 8564_ $$s4180957$$uhttps://zaguan.unizar.es/record/146914/files/texto_completo.pdf$$yVersión publicada
000146914 8564_ $$s2397592$$uhttps://zaguan.unizar.es/record/146914/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000146914 909CO $$ooai:zaguan.unizar.es:146914$$particulos$$pdriver
000146914 951__ $$a2026-01-12-12:51:06
000146914 980__ $$aARTICLE