000146963 001__ 146963
000146963 005__ 20241129141115.0
000146963 0247_ $$2doi$$a10.1021/jacs.4c11111
000146963 0248_ $$2sideral$$a140785
000146963 037__ $$aART-2024-140785
000146963 041__ $$aeng
000146963 100__ $$aDownes, Marley
000146963 245__ $$aSynthesis of three isoelemental MXenes and their structure–property relationships
000146963 260__ $$c2024
000146963 5060_ $$aAccess copy available to the general public$$fUnrestricted
000146963 5203_ $$aThe MXene family has rapidly expanded since its discovery in2011 to include nearly 50 unique MXenes, not accounting for solid solutionsand diverse surface terminations. However, a question raised since theirdiscovery has been: What is the effect of n? In other words, how does thenumber of layers affect the MXene properties? To date, no direct study of theimpact of n has been conducted due to the lack of isoelemental MXenecompositions spanning more than two n values. Herein, we report on a systemof three MXenes with identical M-site chemistries, (Mo2/3V1/3)n+1CnTx (n = 1,2, and 3), allowing for the study of MXene structure−property relationshipsacross n, for the first time. Chemical analysis of the samples shows completeand partial ordering of the M-elements in the n = 2 and 3 samples, respectively.We show that sample stability gradually evolves as n is increased from 1 to 3,while electronic and electrochemical properties exhibit more significant changes in going from n = 1 to 2 than from n = 2 to 3.
000146963 536__ $$9info:eu-repo/grantAgreement/ES/AEI/CEX2023-001286-S$$9info:eu-repo/grantAgreement/ES/DGA/E13-23R$$9info:eu-repo/grantAgreement/ES/MICINN-AEI/PRTR-C17.I1$$9info:eu-repo/grantAgreement/ES/MICINN/PID2019-104739GB-100
000146963 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000146963 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000146963 700__ $$aShuck, Christopher E.
000146963 700__ $$aWang, Ruocun John
000146963 700__ $$aMichalowski, Pawel Piotr
000146963 700__ $$aShochat, Jonathan
000146963 700__ $$aZhang, Danzhen
000146963 700__ $$aShekhirev, Mikhail
000146963 700__ $$aYang, Yizhou
000146963 700__ $$aZaluzec, Nestor J.
000146963 700__ $$0(orcid)0000-0002-2071-9093$$aArenal, Raul
000146963 700__ $$aMay, Steven J.
000146963 700__ $$aGogotsi, Yury
000146963 773__ $$g146, 45 (2024), 31159-31168$$pJ. Am. Chem. Soc.$$tJournal of the American Chemical Society$$x0002-7863
000146963 8564_ $$s4525628$$uhttps://zaguan.unizar.es/record/146963/files/texto_completo.pdf$$yVersión publicada
000146963 8564_ $$s3038344$$uhttps://zaguan.unizar.es/record/146963/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000146963 909CO $$ooai:zaguan.unizar.es:146963$$particulos$$pdriver
000146963 951__ $$a2024-11-29-13:25:07
000146963 980__ $$aARTICLE