000148002 001__ 148002
000148002 005__ 20250113143111.0
000148002 0247_ $$2doi$$a10.1039/d1ta10385g
000148002 0248_ $$2sideral$$a128465
000148002 037__ $$aART-2022-128465
000148002 041__ $$aeng
000148002 100__ $$aBenzaqui, Marvin
000148002 245__ $$aA robust eco-compatible microporous iron coordination polymer for CO2 capture
000148002 260__ $$c2022
000148002 5203_ $$aIron(iii) carboxylate based metal organic frameworks (MOFs)/porous coordination polymers (PCPs) have sparked great interest owing to their high structural diversity and tunable porosity, excellent stability, tailored functionality and their scalability as well as green synthesis associated with their biocompatible and biodegradable character. Herein, we present a new robust Fe(iii) based PCP (labelled MIL-178(Fe)) built up from chains of corner sharing Fe octahedra interconnected by 1, 2, 4-benzene tricarboxylic acid, delimiting one dimensional narrow pore channels (pore diameter < 4.5 angstrom) decorated with polar groups (mu(2)-OH and -CO2H functions). These structural and chemical features are suitable for the selective adsorption of CO2. MIL-178(Fe) was synthesized following a simple and green protocol in water under near ambient conditions using non-toxic reactants, allowing the production of sub-micrometer sized MIL-178(Fe) particles in a large amount (30 g). As shown by single-gas isotherms and CO2/N-2 co-adsorption experiments as well as molecular simulations, this material exhibits a moderate CO2 capacity at low pressure but a high CO2/N-2 selectivity. This is fully consistent with the presence of mu(2)-OH groups acting as CO2 adsorption sites, as revealed from both molecular simulations and in situ PXRD experiments. Finally, the good compatibility of this MOF with the elastomer block copolymer Pebax (R)-3533 allowed the processing of homogeneous and defect-free mixed matrix membranes with a MIL-178(Fe) loading of up to 25 wt% that outperformed pure Pebax (R)-3533 membranes for CO2/N-2 separation.
000148002 536__ $$9info:eu-repo/grantAgreement/EC/FP7/608490/EU/Energy efficient MOF-based Mixed Matrix Membranes for CO2 Capture/M4CO2
000148002 540__ $$9info:eu-repo/semantics/closedAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000148002 590__ $$a11.9$$b2022
000148002 591__ $$aCHEMISTRY, PHYSICAL$$b24 / 161 = 0.149$$c2022$$dQ1$$eT1
000148002 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b32 / 343 = 0.093$$c2022$$dQ1$$eT1
000148002 591__ $$aENERGY & FUELS$$b11 / 119 = 0.092$$c2022$$dQ1$$eT1
000148002 592__ $$a3.156$$b2022
000148002 593__ $$aChemistry (miscellaneous)$$c2022$$dQ1
000148002 593__ $$aRenewable Energy, Sustainability and the Environment$$c2022$$dQ1
000148002 593__ $$aMaterials Science (miscellaneous)$$c2022$$dQ1
000148002 594__ $$a22.0$$b2022
000148002 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000148002 700__ $$aWahiduzzaman, Mohammad
000148002 700__ $$aZhao, Heng
000148002 700__ $$aHasan, Md Rafiul
000148002 700__ $$aSteenhaut, Timothy
000148002 700__ $$aSaad, Ali
000148002 700__ $$aMarrot, Jérôme
000148002 700__ $$aNormand, Périne
000148002 700__ $$aGreneche, Jean-Marc
000148002 700__ $$aHeymans, Nicolas
000148002 700__ $$aDe Weireld, Guy
000148002 700__ $$aTissot, Antoine
000148002 700__ $$aShepard, William
000148002 700__ $$aFilinchuk, Yaroslav
000148002 700__ $$aHermans, Sophie
000148002 700__ $$aCarn, Florent
000148002 700__ $$aManlankowska, Magdalena
000148002 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, Carlos$$uUniversidad de Zaragoza
000148002 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, Joaquín$$uUniversidad de Zaragoza
000148002 700__ $$aMaurin, Guillaume
000148002 700__ $$aSteunou, Nathalie
000148002 700__ $$aSerre, Christian
000148002 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000148002 773__ $$g10 (2022), 8535–8545$$pJ. mater. chem. A$$tJournal of Materials Chemistry A$$x2050-7488
000148002 8564_ $$s1501751$$uhttps://zaguan.unizar.es/record/148002/files/texto_completo.pdf$$yVersión publicada
000148002 8564_ $$s2589865$$uhttps://zaguan.unizar.es/record/148002/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000148002 909CO $$ooai:zaguan.unizar.es:148002$$particulos$$pdriver
000148002 951__ $$a2025-01-13-14:30:27
000148002 980__ $$aARTICLE