000148537 001__ 148537
000148537 005__ 20250120165541.0
000148537 0247_ $$2doi$$a10.1016/j.ces.2014.07.046
000148537 0248_ $$2sideral$$a88540
000148537 037__ $$aART-2015-88540
000148537 041__ $$aeng
000148537 100__ $$0(orcid)0000-0003-1273-2690$$aSorribas, Sara$$uUniversidad de Zaragoza
000148537 245__ $$aPervaporation and membrane reactor performance of polyimide based mixed matrix membranes containing MOF HKUST-1
000148537 260__ $$c2015
000148537 5060_ $$aAccess copy available to the general public$$fUnrestricted
000148537 5203_ $$aMixed matrix membranes (MMM) containing MOF Cu3(BTC)2 (HKUST-1) at 20–40 wt% loading have been prepared using commercial polyimide (PI) Matrimid® 5218 as polymer matrix. With the addition of this hydrophilic MOF, the water/ethanol separation via pervaporation was improved by increasing the water flux from 0.24 kg m−2 h−1 for bare PI up to 0.43 kg m−2 h−1 with 40 wt% Cu3(BTC)2 MMM without significant changes in the separation factor (>200). Due to their selective water permeation, these MMMs have been used to displace equilibrium in the esterification of acetic acid with ethanol. By coupling separation by membrane and the reaction in the same device, the conversion obtained at the same feed rate and catalyst loading was higher than that achieved without any membrane. At 70 °C the membrane reactor reached a conversion of 70%, higher than the equilibrium value (66%).
000148537 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/IPT2011-0878-420000$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2010-15870
000148537 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000148537 590__ $$a2.75$$b2015
000148537 591__ $$aENGINEERING, CHEMICAL$$b27 / 135 = 0.2$$c2015$$dQ1$$eT1
000148537 592__ $$a1.022$$b2015
000148537 593__ $$aChemical Engineering (miscellaneous)$$c2015$$dQ1
000148537 593__ $$aIndustrial and Manufacturing Engineering$$c2015$$dQ1
000148537 593__ $$aChemistry (miscellaneous)$$c2015$$dQ1
000148537 593__ $$aApplied Mathematics$$c2015$$dQ2
000148537 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000148537 700__ $$aKudasheva, Alina
000148537 700__ $$aAlmendro, Eduardo
000148537 700__ $$0(orcid)0000-0002-9934-1707$$aZornoza, Beatriz
000148537 700__ $$0(orcid)0000-0003-0297-3503$$aIglesia, Oscar de la
000148537 700__ $$0(orcid)0000-0002-4954-1188$$aTellez, Carlos$$uUniversidad de Zaragoza
000148537 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, Joaquín$$uUniversidad de Zaragoza
000148537 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000148537 773__ $$g124 (2015), 37-44$$pChem. Eng. Sci.$$tCHEMICAL ENGINEERING SCIENCE$$x0009-2509
000148537 8564_ $$s666613$$uhttps://zaguan.unizar.es/record/148537/files/texto_completo.pdf$$yPostprint
000148537 8564_ $$s1197257$$uhttps://zaguan.unizar.es/record/148537/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000148537 909CO $$ooai:zaguan.unizar.es:148537$$particulos$$pdriver
000148537 951__ $$a2025-01-20-14:52:36
000148537 980__ $$aARTICLE