148633 20250121144848.0 doi 10.1002/adfm.201203462 sideral 85410 ART-2014-85410 eng Rodenas, T. Visualizing mof mixed matrix membranes at the nanoscale: towards structure-performance relationships in co2/ch4 separation over nh2-mil-53(al)@pi 2014 Access copy available to the general public Unrestricted Mixed matrix membranes (MMMs) composed of metal organic framework (MOF) fillers embedded in a polymeric matrix represent a promising alternative for CO2 removal from natural gas and biogas. Here, MMMs based on NH2-MIL-53(Al) MOF and polyimide are successfully synthesized with MOF loadings up to 25 wt% and different thicknesses. At 308 K and ΔP = 3 bar, the incorporation of the MOF filler enhances CO2 permeability with respect to membranes based on the neat polymer, while preserving the relatively high separation factor. The rate of solvent evaporation after membrane casting proves key for the final configuration and dispersion of the MOF in the membrane. Fast solvent removal favours the contraction of the MOF structure to its narrow pore framework configuration, resulting in enhanced separation factor and, particularly, CO2 permeability. The study reveals an excellent filler-polymer contact, with ca. 0.11% void volume fraction, for membranes based on the amino-functionalized MOF, even at high filler loadings (25 wt%). By providing precise and quantitative insight into key structural features at the nanoscale range, the approach provides feedback to the membrane casting process and therefore it represents an important advancement towards the rational design of mixed matrix membranes with enhanced structural features and separation performance. info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 11.805 2014 CHEMISTRY, PHYSICAL 9 / 138 = 0.065 2014 Q1 T1 MATERIALS SCIENCE, MULTIDISCIPLINARY 12 / 257 = 0.047 2014 Q1 T1 CHEMISTRY, MULTIDISCIPLINARY 12 / 154 = 0.078 2014 Q1 T1 NANOSCIENCE & NANOTECHNOLOGY 6 / 78 = 0.077 2014 Q1 T1 PHYSICS, CONDENSED MATTER 8 / 66 = 0.121 2014 Q1 T1 PHYSICS, APPLIED 7 / 141 = 0.05 2014 Q1 T1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Van Dalen, M. García-Pérez, E. Serra-Crespo, P. Zornoza, B. (orcid)0000-0002-9934-1707 Kapteijn, F. Gascon, J. 24, 2 (2014), 249-256 Adv. funct. mater. Advanced Functional Materials 1616-301X 343179 http://zaguan.unizar.es/record/148633/files/texto_completo.pdf Postprint 1636630 http://zaguan.unizar.es/record/148633/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:148633 articulos driver 2025-01-21-14:47:52 ARTICLE