doi:10.1039/c9dt04816bengRubín, JavierBadía-Romano, LauraLuis, FernandoMereacre, ValeriuProdius, DenisArauzo, AnaBartolomé, FernandoBartolomé, JuanMagnetic chains of Fe3 clusters in the {Fe3YO2} butterfly molecular compoundART-2020-117220The "butterfly" molecule [Fe3Y(µ3-O)2(CCl3COO)8(H2O)(THF)3] (in brief {Fe3YO2}) includes three Fe3+ ions which build a robust Fe3 cluster with a strong intracluster antiferromagnetic exchange and a total spin S = 5/2. It represents the starting magnetic system to study further interactions with magnetic rare earths when Y is replaced with lanthanides. We present heat capacity and equilibrium susceptibility measurements below 2 K, which show that each cluster has a sizeable magnetic anisotropy pointing to the existence of intercluster interactions. However, no phase transition to a long-range magnetically ordered phase is observed down to 20 mK. The intercluster interaction is analysed in the framework of the one-dimensional Blume-Capel model with an antiferromagnetic chain interaction constant J/kB = -40(2) mK between Fe3 cluster spins, and a uniaxial anisotropy with parameter D/kB = -0.56(3) K. This is associated to single chains of Fe3 clusters oriented along the shortest intercluster distances displayed by the crystal structure of {Fe3YO2}. Ac susceptibility measurements reveal that the magnetic relaxation is dominated by a quantum tunnelling process below 0.2 K, and by thermally activated processes above this temperature. The experimental activation energy of this single chain magnet, Ea/kB = 3.4(6) K, can be accounted for by the combination of contributions arising from single-molecule magnetic anisotropy and spin-spin correlations along the chains.2020http://zaguan.unizar.es/record/14913210.1039/c9dt04816bhttp://zaguan.unizar.es/record/149132oai:zaguan.unizar.es:149132info:eu-repo/grantAgreement/ES/DGA/E09-17Rinfo:eu-repo/grantAgreement/ES/DGA/E12-R17info:eu-repo/grantAgreement/ES/MCINN/MAT2017-83468-Rinfo:eu-repo/grantAgreement/ES/MCINN/PCI2018-093116info:eu-repo/grantAgreement/ES/MICINN/RTI2018-096075-B-C21info:eu-repo/grantAgreement/EUR/MOLSPIN-COST/CA15128Dalton Transactions 49, 9 (2020), 2979-2988All rights reservedhttp://www.europeana.eu/rights/rr-f/info:eu-repo/semantics/openAccess