149765 20251017144551.0 doi 10.1039/c9dt02047k sideral 116318 ART-2019-116318 eng Bartolomé, E. High relaxation barrier in neodymium furoate-based field-induced SMMs 2019 Access copy available to the general public Unrestricted Two new neodymium molecular magnets of formula {Nd(a-fur)3(H2O)2]·DMF}n (1) and {Nd0.065La0.935(a-fur)3(H2O)2]}n (2), a-fur = C4H3OCOO, have been synthesized. In (1) the furoate ligands, in bidentate bridging mode, consolidate zig-zag chains running along the a-direction. Compound (2) is a magnetically diluted complex of a polymeric chain along the b-axis. Heat capacity, dc magnetization and ac susceptibility measurements have been performed from 1.8 K up to room temperature. Ab initio calculations yielded the gyromagnetic factors gx* = 0.52, gy* = 1.03, gz* = 4.41 for (1) and gx* = 1.35, gy* = 1.98, gz* = 3.88 for (2), and predicted energy gaps of ¿/kB = 125.5 K (1) and ¿/kB = 58.8 K (2). Heat capacity and magnetometry measurements agree with these predictions, and confirm the non-negligible transversal anisotropy of the Kramers doublet ground state. A weak intrachain antiferromagnetic interaction J'/kB = -3.15 × 10-3 K was found for (1). No slow relaxation is observed at H = 0, attributed to the sizable transverse anisotropy component, and/or dipolar or exchange interactions enhancing the quantum tunnelling probability. Under an external applied field as small as 80 Oe, two slow relaxation processes appear: above 3 K the first relaxation mechanism is associated to a combination of Orbach process, with a sizeable activation energy U/kB = 121 K at 1.2 kOe for (1), Raman and direct processes; the second, slowest relaxation mechanism is associated to a direct process, affected by phonon-bottleneck effect. For complex (2) a smaller U/kB = 61 K at 1.2 kOe is found, together with larger g*-transversal terms, and the low-frequency process is quenched. The reported complexes represent rare polymeric Nd single-ion magnets exhibiting high activation energies among the scarce Nd(iii) family. © 2019 The Royal Society of Chemistry. info:eu-repo/grantAgreement/ES/DGA/E12-R17 info:eu-repo/grantAgreement/ES/MINECO/MAT2017-83468-R info:eu-repo/semantics/openAccess by-nc https://creativecommons.org/licenses/by-nc/4.0/deed.es 4.174 2019 CHEMISTRY, INORGANIC & NUCLEAR 5 / 45 = 0.111 2019 Q1 T1 1.048 2019 Inorganic Chemistry 2019 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Arauzo, A. Universidad de Zaragoza (orcid)0000-0002-5999-341X Luzón, J. (orcid)0000-0002-9208-0807 Melnic, S. Shova, S. Prodius, D. Nlebedim, I. C. Bartolomé, F. Universidad de Zaragoza (orcid)0000-0002-0047-1772 Bartolomé, J. (orcid)0000-0002-6517-1236 2003 395 Universidad de Zaragoza Dpto. Física Materia Condensa. Área Física Materia Condensada 48, 41 (2019), 15386-15396 Dalton Trans. Dalton Transactions 1477-9226 4725664 http://zaguan.unizar.es/record/149765/files/texto_completo.pdf Versión publicada 2551373 http://zaguan.unizar.es/record/149765/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:149765 articulos driver 2025-10-17-14:11:54 ARTICLE