000150172 001__ 150172
000150172 005__ 20251017144546.0
000150172 0247_ $$2doi$$a10.1021/cm052521x
000150172 0248_ $$2sideral$$a92450
000150172 037__ $$aART-2006-92450
000150172 041__ $$aeng
000150172 100__ $$aVertelman, EJM
000150172 245__ $$aThe influence of defects on the electron-transfer and magnetic properties of RbxMn[Fe(CN)(6)](y)center dot zH(2)O
000150172 260__ $$c2006
000150172 5203_ $$aThe synthesis and detailed characterization of a few samples of the compound RbxMn[Fe(CN)6]y‚zH2O are described. The composition of the materials significantly depends on the applied preparative conditions. Analysis of spectroscopic results (FTIR, Raman, 57Fe Mo¨ssbauer, XPS) and X-ray powderdiffraction data yielded a further assessment of the difference in structural features in terms of the amount of Fe(CN)6 vacancies and the associated number of water molecules. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structures that appear to be associated with the synthetic method used.
000150172 540__ $$9info:eu-repo/semantics/closedAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000150172 590__ $$a5.104$$b2006
000150172 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b12 / 175 = 0.069$$c2006$$dQ1$$eT1
000150172 591__ $$aCHEMISTRY, PHYSICAL$$b12 / 108 = 0.111$$c2006$$dQ1$$eT1
000150172 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000150172 700__ $$aMaccallini, E
000150172 700__ $$aGournis, D
000150172 700__ $$aRudolf, P
000150172 700__ $$aBakas, T
000150172 700__ $$0(orcid)0000-0002-9208-0807$$aLuzon, J
000150172 700__ $$aBroer, R
000150172 700__ $$aPugzlys, A
000150172 700__ $$aLummen, TTA
000150172 700__ $$avan Loosdrecht, PHM
000150172 700__ $$avan Koningsbruggen, PJ.
000150172 773__ $$g18, 7 (2006), 1951-1963$$pChem. mater.$$tChemistry of materials$$x0897-4756
000150172 8564_ $$s266006$$uhttps://zaguan.unizar.es/record/150172/files/texto_completo.pdf$$yVersión publicada
000150172 8564_ $$s3124627$$uhttps://zaguan.unizar.es/record/150172/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000150172 909CO $$ooai:zaguan.unizar.es:150172$$particulos$$pdriver
000150172 951__ $$a2025-10-17-14:09:39
000150172 980__ $$aARTICLE