000150571 001__ 150571
000150571 005__ 20251017144650.0
000150571 0247_ $$2doi$$a10.1016/j.molliq.2024.126655
000150571 0248_ $$2sideral$$a142679
000150571 037__ $$aART-2025-142679
000150571 041__ $$aeng
000150571 100__ $$aSancho-Blasco, Mónica
000150571 245__ $$aThermophysical characterization of lidocaine:camphor:thymol or l-menthol eutectic mixtures: Experimental and modelling
000150571 260__ $$c2025
000150571 5060_ $$aAccess copy available to the general public$$fUnrestricted
000150571 5203_ $$aKnowing the values of the thermodynamic and transport properties of fluids is essential for their implementation in different fields. In addition, their analysis allows us to understand the intermolecular interactions which is useful in the subsequent design of processes. In this work, two ternary eutectic mixtures composed of lidocaine, camphor, and thymol or l-menthol were studied. Six thermophysical properties were measured at 0.1 MPa and at various temperatures. Density values up to 65 MPa were also determined. From these data, different properties were calculated, such as isobaric expansibility, isentropic and isothermal compressibility, internal pressure, and critical temperature, among others. The mixture with thymol was the most dense, structured, and viscous. The correlations and models used showed small deviations between the experimental and estimated values. The deviations of the density and isobaric molar heat capacity predicted with PC-SAFT equation of state were lower than 1.4 % and 3.1 %, respectively. The interactions between lidocaine and thymol were the strongest. On the other hand, camphor was shown to be a steric hindrance to binary interactions.
000150571 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E31-23R
000150571 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
000150571 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000150571 700__ $$aPastor, Jorge L.
000150571 700__ $$0(orcid)0000-0002-8354-7436$$aMuñoz-Embid, José$$uUniversidad de Zaragoza
000150571 700__ $$0(orcid)0000-0003-3632-6822$$aLafuente, Carlos$$uUniversidad de Zaragoza
000150571 700__ $$0(orcid)0000-0003-1810-9488$$aArtal, Manuela$$uUniversidad de Zaragoza
000150571 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000150571 773__ $$g417 (2025), 126655 [10 pp.]$$pJ. mol. liq.$$tJournal of Molecular Liquids$$x0167-7322
000150571 8564_ $$s970252$$uhttps://zaguan.unizar.es/record/150571/files/texto_completo.pdf$$yVersión publicada
000150571 8564_ $$s2645951$$uhttps://zaguan.unizar.es/record/150571/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000150571 909CO $$ooai:zaguan.unizar.es:150571$$particulos$$pdriver
000150571 951__ $$a2025-10-17-14:36:17
000150571 980__ $$aARTICLE