000150690 001__ 150690
000150690 005__ 20250319143309.0
000150690 0247_ $$2doi$$a10.1002/chem.202404657
000150690 0248_ $$2sideral$$a142807
000150690 037__ $$aART-2025-142807
000150690 041__ $$aeng
000150690 100__ $$aGómez-España, Alejandra
000150690 245__ $$aRhodium(III)-NSi Catalyzed Styrene Hydrosilylation: Evidence of the Hemilabile Character of NSi-Type Ligands
000150690 260__ $$c2025
000150690 5060_ $$aAccess copy available to the general public$$fUnrestricted
000150690 5203_ $$aThe 18e saturated rhodium(III) species [Rh(H)(X)(κ2‐NSitBu2)(bipyMe2)] (NSitBu2={4‐methylpyridine‐2‐yloxy}ditertbutylsilyl; bipyMe2=4,4'‐dimethylbipyridine) (X=Cl, 1; OTf, 2) have been prepared and characterized by NMR spectroscopy and in the case of 2 it has been possible to determine its solid‐state structure by X‐ray diffraction. Complex 1 has proven to be an effective catalyst precursor for the reaction of styrene derivatives with hydrosilanes in CD2Cl2. However, under catalytic conditions complex 2 decomposes. The performance of the 1‐catalyzed reaction of styrene with hydrosilanes strongly depends on the nature of the silane, the best catalytic performance was achieved using HSiMe2Ph. Theoretical and 1H NMR studies indicate that the hemilabile nature of the NSi ligand is key to understanding the catalytic activity of compound 1.
000150690 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E42-23R$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-122763NB-I00$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-126212OB-I00$$9info:eu-repo/grantAgreement/ES/MICINN/PID2023-148113OB-I00$$9info:eu-repo/grantAgreement/ES/UZ/JIUZ-2023-CIE-10
000150690 540__ $$9info:eu-repo/semantics/embargoedAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000150690 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000150690 700__ $$aPadilla, Marina
000150690 700__ $$aMartínez de Morentin, Aitor
000150690 700__ $$0(orcid)0000-0002-7063-1292$$aGarcía-Orduña, Pilar
000150690 700__ $$aHuertos, Miguel A.
000150690 700__ $$0(orcid)0000-0001-6089-6126$$aMunarriz, Julen$$uUniversidad de Zaragoza
000150690 700__ $$0(orcid)0000-0002-0497-1969$$aFernández-Alvarez, Francisco J.$$uUniversidad de Zaragoza
000150690 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000150690 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000150690 773__ $$g(2025), [9 pp.]$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000150690 8564_ $$s637989$$uhttps://zaguan.unizar.es/record/150690/files/texto_completo.pdf$$yVersión publicada$$zinfo:eu-repo/date/embargoEnd/2026-01-21
000150690 8564_ $$s3033322$$uhttps://zaguan.unizar.es/record/150690/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada$$zinfo:eu-repo/date/embargoEnd/2026-01-21
000150690 909CO $$ooai:zaguan.unizar.es:150690$$particulos$$pdriver
000150690 951__ $$a2025-03-19-14:32:22
000150690 980__ $$aARTICLE