000151148 001__ 151148
000151148 005__ 20251017144608.0
000151148 0247_ $$2doi$$a10.3390/sym13091688
000151148 0248_ $$2sideral$$a125800
000151148 037__ $$aART-2021-125800
000151148 041__ $$aeng
000151148 100__ $$aPark S.
000151148 245__ $$aStructural investigation into magnetic spin orders of a manganese phosphatic oxyhydroxide, mn5 [(Po4 )2 (po3 (oh))2 ](hoh)4
000151148 260__ $$c2021
000151148 5060_ $$aAccess copy available to the general public$$fUnrestricted
000151148 5203_ $$aThe ferri-and antiferromagnetic structures of a hureaulite-type synthetic compound, Mn2+ 5(PO4 )2 (PO3 (OH))2 (HOH)4, were elucidated by high-resolution neutron powder diffraction in combination with magnetic susceptibility and heat capacity measurements. At 6.17 K, the para-magnetic phase (space group: C2/c) transforms to inherit a ferrimagnetic order (magnetic space group: C2' /c' ), followed at 1.86 K by an incommensurately modulated antiferromagnetic order (magnetic superspace group: P21 /c.1' (a0¿)00s with the propagation vector k(0.523(2), 0, 0.055(1)). In the ferrimagnetic state, antiferromagnetic interactions are dominant for both intra and inter pentamers of Mn2+ (O, HOH)6 octahedra. Differently aligned spin-canting sublattices seen in the ferrimagnetic models at 3.4, 4.5, and 6.1 K explain a weak ferromagnetism in the title compound. The observation of magnetic moments vigorously changing in a small temperature range of 6.1–1.5 K adumbrates a high complexity of interplaying structural and magnetic orders in this manganese phosphatic oxyhydroxide.
000151148 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttps://creativecommons.org/licenses/by/4.0/deed.es
000151148 590__ $$a2.94$$b2021
000151148 591__ $$aMULTIDISCIPLINARY SCIENCES$$b34 / 74 = 0.459$$c2021$$dQ2$$eT2
000151148 592__ $$a0.54$$b2021
000151148 593__ $$aChemistry (miscellaneous)$$c2021$$dQ2
000151148 593__ $$aPhysics and Astronomy (miscellaneous)$$c2021$$dQ2
000151148 593__ $$aComputer Science (miscellaneous)$$c2021$$dQ2
000151148 594__ $$a4.3$$b2021
000151148 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000151148 700__ $$aHartl A.
000151148 700__ $$aSheptyakov D.
000151148 700__ $$aHoelzel M.
000151148 700__ $$0(orcid)0000-0002-5999-341X$$aArauzo A.$$uUniversidad de Zaragoza
000151148 7102_ $$10$$2X$$aUniversidad de Zaragoza$$bServ.Gral. Apoyo Investigación$$cServicios. Div.Caract.Físi.Quí
000151148 773__ $$g13, 9 (2021), 1688 [18 pp.]$$pSymmetry (Basel)$$tSymmetry$$x2073-8994
000151148 8564_ $$s591630$$uhttps://zaguan.unizar.es/record/151148/files/texto_completo.pdf$$yVersión publicada
000151148 8564_ $$s2733716$$uhttps://zaguan.unizar.es/record/151148/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000151148 909CO $$ooai:zaguan.unizar.es:151148$$particulos$$pdriver
000151148 951__ $$a2025-10-17-14:15:59
000151148 980__ $$aARTICLE