000151287 001__ 151287
000151287 005__ 20250307114715.0
000151287 0247_ $$2doi$$a10.1039/d0na00744g
000151287 0248_ $$2sideral$$a124089
000151287 037__ $$aART-2021-124089
000151287 041__ $$aeng
000151287 100__ $$0(orcid)0000-0003-4333-6498$$aCastillo-Vallés, M.
000151287 245__ $$aMicrofluidics for the rapid and controlled preparation of organic nanotubes of bent-core based dendrimers
000151287 260__ $$c2021
000151287 5060_ $$aAccess copy available to the general public$$fUnrestricted
000151287 5203_ $$aRecently, bent-core molecules have emerged as excellent building blocks for the obtaining of nanostructures in solvents. Herein, we report the use of a coaxial microfluidic system as a promising tool to control the self-assembly of non-conventional bent-core amphiphiles. Moreover, a TEM study to comprehend the hierarchical self-assembly process in solution was carried out. The proposed tool provides both a cost-effective platform to save hard-to-synthesise reagents and a rapid method to screen a plethora of different parameters, i.e., THF/water ratio, residence time, concentration of the amphiphile, temperature and pH. The experiments allowed to test for the first time the suitability of microfluidics for the self-assembly of bent-core molecules, as well as the study of a range of conditions to control the assembly of different nanostructures in a rapid and controlled manner. Additionally, organic nanostructures were combined with gold nanoparticles to prepare nanocomposites with enhanced properties. Both organic and hybrid nanostructures were also obtained in the solid state. These results may inspire scientists working on supramolecular chemistry and bent-core molecules expanding the scope of microfluidic systems for the self-assembly of other low-molecular-weight compounds.
000151287 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E47-20R$$9info:eu-repo/grantAgreement/ES/UZ-DGA/T57-20R$$9info:eu-repo/grantAgreement/ES/MICINN-FEDER/MAT2015-66208-C3-1-P$$9info:eu-repo/grantAgreement/ES/MICINN-FEDER/PGC2018-093761-B-C31$$9info:eu-repo/grantAgreement/ES/MICINN-FEDER/PGC2018-097583-B-I00$$9info:eu-repo/grantAgreement/ES/MICINN/RTI2018-099019-A-I00$$9info:eu-repo/grantAgreement/ES/MINECO/BES-2016-078753
000151287 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000151287 590__ $$a5.598$$b2021
000151287 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b111 / 344 = 0.323$$c2021$$dQ2$$eT1
000151287 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b56 / 179 = 0.313$$c2021$$dQ2$$eT1
000151287 591__ $$aNANOSCIENCE & NANOTECHNOLOGY$$b55 / 108 = 0.509$$c2021$$dQ3$$eT2
000151287 592__ $$a1.043$$b2021
000151287 593__ $$aAtomic and Molecular Physics, and Optics$$c2021$$dQ1
000151287 593__ $$aMaterials Science (miscellaneous)$$c2021$$dQ1
000151287 593__ $$aEngineering (miscellaneous)$$c2021$$dQ1
000151287 593__ $$aBioengineering$$c2021$$dQ1
000151287 594__ $$a5.7$$b2021
000151287 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000151287 700__ $$0(orcid)0000-0003-1378-0571$$aRomero, P.
000151287 700__ $$0(orcid)0000-0002-6873-5244$$aSebastián, V.$$uUniversidad de Zaragoza
000151287 700__ $$0(orcid)0000-0003-4416-1036$$aRos, M.B.$$uUniversidad de Zaragoza
000151287 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000151287 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000151287 773__ $$g3, 6 (2021), 1682-1689$$tNanoscale Advances$$x2516-0230
000151287 8564_ $$s891326$$uhttps://zaguan.unizar.es/record/151287/files/texto_completo.pdf$$yVersión publicada
000151287 8564_ $$s2777178$$uhttps://zaguan.unizar.es/record/151287/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000151287 909CO $$ooai:zaguan.unizar.es:151287$$particulos$$pdriver
000151287 951__ $$a2025-03-07-09:31:23
000151287 980__ $$aARTICLE