000151493 001__ 151493 000151493 005__ 20250310131044.0 000151493 0247_ $$2doi$$a10.3390/ijms22115740 000151493 0248_ $$2sideral$$a126591 000151493 037__ $$aART-2021-126591 000151493 041__ $$aeng 000151493 100__ $$aCervera-Procas R. 000151493 245__ $$aA highly versatile polymer network based on liquid crystalline dendrimers 000151493 260__ $$c2021 000151493 5060_ $$aAccess copy available to the general public$$fUnrestricted 000151493 5203_ $$aHighly functional macromolecules with a well-defined architecture are the key to designing efficient and smart materials, and these polymeric systems can be tailored for specific applications in a diverse range of fields. Herein, the formation of a new liquid crystalline polymeric network based on the crosslinking of dendrimeric entities by the CuI-catalyzed variant of the Huisgen 1, 3-dipolar cycloaddition of azides and alkynes to afford 1, 2, 3-triazoles is reported. The polymeric material obtained in this way is easy to process and exhibits a variety of properties, which include mesomorphism, viscoelastic behavior, and thermal contraction. The porous microstructure of the polymer network determines its capability to absorb solvent molecules and to encapsulate small molecules, like organic dyes, which can be released easily afterwards. Moreover, all these properties may be easily tuned by modifying the chemical structure of the constituent dendrimers, which makes this system a very interesting one for a number of applications. 000151493 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E47-20R$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/PGC2018-097583-B-I00 000151493 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000151493 590__ $$a6.208$$b2021 000151493 591__ $$aBIOCHEMISTRY & MOLECULAR BIOLOGY$$b69 / 297 = 0.232$$c2021$$dQ1$$eT1 000151493 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b50 / 179 = 0.279$$c2021$$dQ2$$eT1 000151493 592__ $$a1.176$$b2021 000151493 593__ $$aComputer Science Applications$$c2021$$dQ1 000151493 593__ $$aInorganic Chemistry$$c2021$$dQ1 000151493 593__ $$aSpectroscopy$$c2021$$dQ1 000151493 593__ $$aOrganic Chemistry$$c2021$$dQ1 000151493 593__ $$aPhysical and Theoretical Chemistry$$c2021$$dQ1 000151493 593__ $$aMolecular Biology$$c2021$$dQ1 000151493 594__ $$a6.9$$b2021 000151493 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000151493 700__ $$0(orcid)0000-0001-9866-6633$$aSerrano J.-L.$$uUniversidad de Zaragoza 000151493 700__ $$0(orcid)0000-0002-3661-2485$$aOmenat A. 000151493 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica 000151493 773__ $$g22, 11 (2021), 5740 [18 pp.]$$pInt. j. mol. sci.$$tInternational Journal of Molecular Sciences$$x1661-6596 000151493 8564_ $$s3416384$$uhttps://zaguan.unizar.es/record/151493/files/texto_completo.pdf$$yVersión publicada 000151493 8564_ $$s2783249$$uhttps://zaguan.unizar.es/record/151493/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000151493 909CO $$ooai:zaguan.unizar.es:151493$$particulos$$pdriver 000151493 951__ $$a2025-03-10-12:56:57 000151493 980__ $$aARTICLE