000151965 001__ 151965
000151965 005__ 20250321155444.0
000151965 0247_ $$2doi$$a10.3390/ma14164550
000151965 0248_ $$2sideral$$a126174
000151965 037__ $$aART-2021-126174
000151965 041__ $$aeng
000151965 100__ $$aMoyano S.
000151965 245__ $$aStructural diversity of hydrogen-bonded 4-aryl-3, 5-dimethylpyrazoles for supramolecular materials
000151965 260__ $$c2021
000151965 5060_ $$aAccess copy available to the general public$$fUnrestricted
000151965 5203_ $$aThe 1H-pyrazoles have high versatility and ability to form hydrogen-bonded supramolecu-lar materials. In this study, the thermal stability, fluorescence, and H-bonding ability of the studied 3, 5-dimethyl-4-(4-X-phenyl)-1H-pyrazoles showed large differences depending on the terminal sub-stituent. Supramolecular structures were analyzed using X-ray diffraction and Hirshfeld surface calculations. Compounds were found to arrange in different hydrogen-bonded structures, depending on the substitution at the para position of the phenyl ring (X = OCH3, NO2, NH2 ). The methoxy-substituted compounds arranged in dimers through methanol bridges, the nitro-substituted compound formed supramolecular polymers or catemers, and the amino-substituted compound gave rise to a new structure based on a 2D hydrogen-bonded network.
000151965 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E47-20R$$9info:eu-repo/grantAgreement/ES/DGA/E50-20D$$9info:eu-repo/grantAgreement/ES/MCIU-FEDER/PGC2018-093761-B-C31$$9info:eu-repo/grantAgreement/ES/MICIU-FEDER/CTQ2017-83421-P
000151965 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000151965 590__ $$a3.748$$b2021
000151965 591__ $$aMETALLURGY & METALLURGICAL ENGINEERING$$b18 / 79 = 0.228$$c2021$$dQ1$$eT1
000151965 591__ $$aPHYSICS, CONDENSED MATTER$$b28 / 69 = 0.406$$c2021$$dQ2$$eT2
000151965 591__ $$aPHYSICS, APPLIED$$b56 / 161 = 0.348$$c2021$$dQ2$$eT2
000151965 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b177 / 344 = 0.515$$c2021$$dQ3$$eT2
000151965 591__ $$aCHEMISTRY, PHYSICAL$$b85 / 165 = 0.515$$c2021$$dQ3$$eT2
000151965 592__ $$a0.604$$b2021
000151965 593__ $$aMaterials Science (miscellaneous)$$c2021$$dQ2
000151965 593__ $$aCondensed Matter Physics$$c2021$$dQ2
000151965 594__ $$a4.7$$b2021
000151965 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000151965 700__ $$0(orcid)0000-0002-9512-3913$$aDiosdado B.
000151965 700__ $$aSan Felices L.
000151965 700__ $$0(orcid)0000-0002-1373-4850$$aElduque A.$$uUniversidad de Zaragoza
000151965 700__ $$0(orcid)0000-0002-7854-6316$$aGiménez R.
000151965 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000151965 773__ $$g14, 16 (2021), 4550 [14 pp.]$$pMaterials (Basel)$$tMaterials$$x1996-1944
000151965 8564_ $$s4204491$$uhttps://zaguan.unizar.es/record/151965/files/texto_completo.pdf$$yVersión publicada
000151965 8564_ $$s2678892$$uhttps://zaguan.unizar.es/record/151965/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000151965 909CO $$ooai:zaguan.unizar.es:151965$$particulos$$pdriver
000151965 951__ $$a2025-03-21-14:40:48
000151965 980__ $$aARTICLE