153609 20251017144551.0 doi 10.1016/j.jpowsour.2025.236837 sideral 143770 ART-2025-143770 eng Thangaian, Kesavan Performance-optimized diatom- [fórmula] anodes for Li-ion batteries by preserving the nanostructured SiO2 shells of diatom microalgae and tailoring oxygen content 2025 Access copy available to the general public Unrestricted Nanostructured silicon oxides (SiOx) are close-to-market anode materials for increasing the energy density of next-generation lithium-ion batteries (LIBs), offering a balance between high capacity and enhanced cycling stability. However, achieving precise control over SiOx composition while maintaining structural integrity remains a challenge. In this study, we pioneer the use of nanostructured diatom-SiO2 frustules from industrially cultured Nitzschia sp. microalgae as a sustainable and tunable precursor for high-performance SiOx anodes via scalable magnesiothermic reduction reaction (MgTR). By optimizing the Mg-to-diatom-SiO2 molar ratio, we demonstrate controlled partial reduction of SiO2, yielding Si nanocrystals embedded within an SiO2 matrix. Notably, we reveal that the preservation of diatom-SiOx nanoporosity is highly sensitive to reaction exothermic conditions and is effectively stabilized by introducing NaCl as a heat scavenger. Tailoring the reactant composition (SiO2:Mg:NaCl = 1:1:2.5) resulted in anodes with superior electrochemical performance, delivering high capacity retention over 200 cycles. Through a comprehensive suite of characterization techniques, we establish the structure–property-performance relationships governing SiOx anode behavior. These findings mark a major advancement in sustainable SiOx anode design, providing a scalable strategy for integrating biologically templated nanostructures into high-performance LIBs. info:eu-repo/grantAgreement/ES/DGA/M4 info:eu-repo/grantAgreement/ES/MICINN/PCI2022-132993 info:eu-repo/semantics/openAccess by https://creativecommons.org/licenses/by/4.0/deed.es info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Ericson, Tove Vullum, Per Erik Alonso-Sánchez, Pedro Svarverud, Annlinn Chen Svensson, Ann Mari Vullum-Bruer, Fride Hahlin, Maria Blanco, Maria Valeria 641 (2025), 236837 [9 pp.] J. power sources JOURNAL OF POWER SOURCES 0378-7753 3592853 http://zaguan.unizar.es/record/153609/files/texto_completo.pdf Versión publicada 2033548 http://zaguan.unizar.es/record/153609/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:153609 articulos driver 2025-10-17-14:11:49 ARTICLE