000156535 001__ 156535
000156535 005__ 20251017144553.0
000156535 0247_ $$2doi$$a10.1039/c9ob02688f
000156535 0248_ $$2sideral$$a117301
000156535 037__ $$aART-2020-117301
000156535 041__ $$aeng
000156535 100__ $$0(orcid)0000-0002-0769-7168$$aAlegre-Requena, Juan V.
000156535 245__ $$aSimple iodoalkyne-based organocatalysts for the activation of carbonyl compounds
000156535 260__ $$c2020
000156535 5060_ $$aAccess copy available to the general public$$fUnrestricted
000156535 5203_ $$aA novel approach for the formation of bisindolylmethane derivatives (BIMs) is described as a proof of concept to evaluate the catalytic capacity of iodoalkynes. The use of these derivatives is reported as an example of simple halogen bond-based organocatalyst. This kind of activation has not been used before for the synthesis of bisindolylmethane derivatives 3. Interestingly, the preparation of 3-(1H-indol-3-yl)-1-phenylbutan-1-one (8) has been also achieved for the first time with an iodoalkyne derivative. We prove the efficiency of this family of new catalysts by developing a simple and easy operational methodology, opening the door to the development of alternative catalysts in the area of halogen bond-based organocatalysts.
000156535 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E07-17R$$9info:eu-repo/grantAgreement/ES/DGA-FSE/E47-17R$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2017-88091-P$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/PGC2018-093761-B-C31
000156535 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttps://creativecommons.org/licenses/by-nc/4.0/deed.es
000156535 590__ $$a3.876$$b2020
000156535 591__ $$aCHEMISTRY, ORGANIC$$b13 / 57 = 0.228$$c2020$$dQ1$$eT1
000156535 592__ $$a0.923$$b2020
000156535 593__ $$aBiochemistry$$c2020$$dQ1
000156535 593__ $$aPhysical and Theoretical Chemistry$$c2020$$dQ1
000156535 593__ $$aOrganic Chemistry$$c2020$$dQ1
000156535 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000156535 700__ $$aValero-Tena, Alberto
000156535 700__ $$0(orcid)0000-0001-9988-0287$$aGiménez Sonsona, Isaac
000156535 700__ $$0(orcid)0000-0001-7636-9187$$aUriel, Santiago$$uUniversidad de Zaragoza
000156535 700__ $$0(orcid)0000-0002-5244-9569$$aPérez Herrera, Raquel$$uUniversidad de Zaragoza
000156535 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000156535 773__ $$g18, 8 (2020), 1594-1601$$pOrg. biomol. chem.$$tOrganic & Biomolecular Chemistry$$x1477-0520
000156535 8564_ $$s3044675$$uhttps://zaguan.unizar.es/record/156535/files/texto_completo.pdf$$yVersión publicada
000156535 8564_ $$s3634448$$uhttps://zaguan.unizar.es/record/156535/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000156535 909CO $$ooai:zaguan.unizar.es:156535$$particulos$$pdriver
000156535 951__ $$a2025-10-17-14:12:27
000156535 980__ $$aARTICLE