000156550 001__ 156550
000156550 005__ 20251017144556.0
000156550 0247_ $$2doi$$a10.1002/ejoc.202500215
000156550 0248_ $$2sideral$$a143918
000156550 037__ $$aART-2025-143918
000156550 041__ $$aeng
000156550 100__ $$aLuque-Gómez, Ana
000156550 245__ $$aEarth‐abundant metal complexes as catalysts for the dehydrogenative coupling of hydrosilanes and alcohols
000156550 260__ $$c2025
000156550 5060_ $$aAccess copy available to the general public$$fUnrestricted
000156550 5203_ $$aThe dehydrogenative coupling of hydrosilanes with alcohols or water is a fundamental transformation in organosilicon chemistry, enabling the synthesis of alkoxysilanes, silanols, and siloxanes—key materials for coatings and adhesives. Traditionally, these reactions have relied on catalysts based on platinum group metals, which are costly and scarce. The development of Earth‐abundant metal (EAM) catalysts offers a sustainable and cost‐effective alternative. This concept article highlights recent advancements in homogeneous EAM catalysis for these transformations, focusing on mechanistic insights, reactivity trends, and catalytic efficiencies. Catalysts based on manganese, iron, cobalt, copper, or zinc are reshaping the field by offering efficient and selective processes for the synthesis of alkoxysilanes, silanols, and siloxanes. Moreover, a key feature of these catalytic systems is their ability to generate dihydrogen as a byproduct, offering potential applications in hydrogen storage and utilization. Despite the good performances of EAM catalysts in the hydrolysis or alcoholysis of silanes, challenges remain, including improving turnover numbers, substrate scope, and catalyst stability. Future developments integrating computational and experimental approaches will be key to optimizing these systems.
000156550 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E42-23R$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-126212OB-I00$$9info:eu-repo/grantAgreement/ES/MICINN/PRE2019-087598
000156550 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000156550 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000156550 700__ $$0(orcid)0000-0003-3144-5320$$aIglesias, Manuel
000156550 773__ $$g(2025), [9 p.]$$pEUR J ORG CHEM$$tEuropean Journal of Organic Chemistry$$x1434-193X
000156550 8564_ $$s3725773$$uhttps://zaguan.unizar.es/record/156550/files/texto_completo.pdf$$yPostprint
000156550 8564_ $$s2445918$$uhttps://zaguan.unizar.es/record/156550/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000156550 909CO $$ooai:zaguan.unizar.es:156550$$particulos$$pdriver
000156550 951__ $$a2025-10-17-14:13:11
000156550 980__ $$aARTICLE