160853 20251017144550.0 doi 10.1016/j.fpsl.2025.101528 sideral 144129 ART-2025-144129 eng Jimenez Estremera, Carlos Universidad de Zaragoza MS-DIAL as efficient tool for the food safety assessment of volatile substances in disposable tableware 2025 Access copy available to the general public Unrestricted In this work, the food safety of disposable tableware with different compositions and uses has been studied. Migration tests of nine commercially disposable tableware made of polypropylene (PP), polystyrene (PS) and cardboard have been performed in four food simulants (ethanol 10 %, ethanol 95 %, acetic acid 3 % and Tenax ®) and analysed by direct-immersion solid-phase microextraction gas chromatography-mass spectrometry (DI-SPME-GC-MS). Mass Spectrometry Data Independent Analysis (MS-DIAL) software was used for identifying the volatile migrants and proved to be a huge step forward to perform non-target analysis in food contact material samples compared to traditional approaches. Our study detected a wide range of additives like plasticizers, lubricants, and inks and non-intentionally added substances (NIAS) like degradation products from polystyrene (oligomers) and polypropylene along with degradation products of antioxidants and UV stabilizers. More than 80 % of the compounds found were non listed substances (NLS) and their potential toxicological risk was estimated on the basis of Cramer’s rules. info:eu-repo/grantAgreement/ES/DGA-FSE/T53-20R info:eu-repo/semantics/openAccess by-nc-nd https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Blazquez-Martín, Javier Aznar, Margarita Universidad de Zaragoza (orcid)0000-0002-0759-9170 Nerín, Cristina Universidad de Zaragoza (orcid)0000-0003-2685-5739 Domeño, Celia Universidad de Zaragoza (orcid)0000-0001-8893-0963 2009 750 Universidad de Zaragoza Dpto. Química Analítica Área Química Analítica 49 (2025), 101528 [16 pp.] Food Packaging and Shelf Life 2214-2894 4006039 http://zaguan.unizar.es/record/160853/files/texto_completo.pdf Versión publicada 2485147 http://zaguan.unizar.es/record/160853/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:160853 articulos driver 2025-10-17-14:11:38 ARTICLE