Proof of concept for a sorption-enhanced reactor with continuous sorbent feeding (CSF): application to green methanol production

González-Pizarro, R. (Universidad de Zaragoza) ; Lasobras, J. (Universidad de Zaragoza) ; Soler, J. (Universidad de Zaragoza) ; Herguido, J. (Universidad de Zaragoza) ; Menéndez, M. (Universidad de Zaragoza)

Resumen: A new reactor for process intensification using sorption enhanced reaction is described. The novelty compared with most experimental work is that a continuous sorbent feeding (CSF) provides a steady state operation. The sorbent increases the reaction rate of a reversible reaction. The reactor is based on the phenomena of segregation of solids in fluidized bed reactors by using a catalyst and a sorbent. Under certain conditions of density and particle size, the two solids segregate and the sorbent may be removed from the bed with only a small content of catalyst. The system has been experimentally tested in the hydrogenation of CO2 to methanol, using a zeolite as sorbent. A significant increase in CO2 conversion was achieved compared with the same reactor without sorbent.

Idioma: Inglés

DOI: 10.1016/j.cej.2025.164562

Año: 2025

Publicado en: Chemical Engineering Journal 517 (2025), 164562 [8 pp.]
ISSN: 1385-8947

Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2022-139819OB-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PDC2022-133066-I00

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)