161062 20251017144605.0 doi 10.1021/acs.energyfuels.4c04818 sideral 144311 ART-2025-144311 eng Almazán, Héctor Universidad de Zaragoza Viability of the Cocapture of CO2 and Impurities from Oxy-Fuel Combustion and Other Processes in Carbon Capture and Storage Technology 2025 Access copy available to the general public Unrestricted The feasibility of cocapturing CO2 with SO2, CO, and (O2 or NO) from unpurified flue gas produced by oxy-fuel combustion and other processes was assessed by determining the influence of the simultaneous presence of these impurities on selected carbon capture and storage (CCS) operational parameters. These parameters were calculated based on experimental results obtained under CCS conditions. The density, vapor–liquid equilibrium, and speed of sound of [CO2 + 3.0038 mol % O2 + 0.09035 mol % SO2 + 0.17032 mol % CO] and [CO2 + 0.1410 mol % NO + 0.09100 mol % SO2 + 0.17002 mol % CO] mixtures were experimentally determined at temperatures between 263 and 373 K and pressures of up to 30 MPa for density and 190 MPa for speed of sound. Joule–Thomson coefficients and isentropic compressibilities of the mixtures were calculated from our experimental results. Using experimental and calculated data, we assessed the predictive capability of the EOS-CG, GERG-2008, and PC-SAFT equations of state. The simultaneous presence of the investigated impurities at the studied concentrations adversely affects the transport and storage steps in CCS; however, the behavior of the NO-containing mixture is very similar to that of pure CO2. The implications of the chemical effects of the impurities were overlooked. info:eu-repo/grantAgreement/ES/DGA/T46-17R info:eu-repo/grantAgreement/ES/DGA/T46-20R info:eu-repo/grantAgreement/ES/DGA/T46-23R info:eu-repo/grantAgreement/ES/MICINN/PID2021-125137OB-I00 info:eu-repo/grantAgreement/ES/MICIU/RTI2018-094488-B-C22 info:eu-repo/semantics/openAccess by https://creativecommons.org/licenses/by/4.0/deed.es info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Fernández, Javier Universidad de Zaragoza (orcid)0000-0001-5256-6055 Blanco, Sofía T. Universidad de Zaragoza (orcid)0000-0003-2632-2916 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 39, 23 (2025), 11173-11186 Energy fuels Energy and Fuels 0887-0624 5437095 http://zaguan.unizar.es/record/161062/files/texto_completo.pdf Versión publicada 3242069 http://zaguan.unizar.es/record/161062/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:161062 articulos driver 2025-10-17-14:15:03 ARTICLE