000162406 001__ 162406
000162406 005__ 20251017144601.0
000162406 0247_ $$2doi$$a10.1002/chem.202501606
000162406 0248_ $$2sideral$$a144995
000162406 037__ $$aART-2025-144995
000162406 041__ $$aeng
000162406 100__ $$aDemonti, Luca
000162406 245__ $$aPlatform Design Enabling Silver(III) Stabilization ─ The Uprise of Ag<sup>III</sup>CF<sub>3</sub> Chemistry?
000162406 260__ $$c2025
000162406 5060_ $$aAccess copy available to the general public$$fUnrestricted
000162406 5203_ $$aUnlike its coinage metal counterparts, copper and gold, silver chemistry remains poorly developed and mostly restricted to the oxidation state +I, which embraces a large variety of coordination environments and types of ligand. Higher oxidation states, that is, +II and +III, are significantly less represented and predominantly adopt a square planar (SP‐4) geometry around the metal center. In particular, well‐defined d8 AgIII compounds are scarce, and include only a handful of examples exhibiting out‐of‐plane silver coordination. This Concept Article summarizes the strategies known to stabilize AgIII, as well as the unusual electronic structures (inverted ligand field) often found in these compounds. The intriguing case study of the expansion in the coordination number in AgIIICF3 compounds will be highlighted.
000162406 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E17-23R$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-122869NB-I00
000162406 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttps://creativecommons.org/licenses/by/4.0/deed.es
000162406 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000162406 700__ $$0(orcid)0000-0002-0204-7713$$aJoven-Sancho, Daniel$$uUniversidad de Zaragoza
000162406 700__ $$0(orcid)0000-0002-2492-625X$$aBaya, Miguel$$uUniversidad de Zaragoza
000162406 700__ $$aNebra, Noel
000162406 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000162406 773__ $$g31, 44 (2025), e202501606 [13 pp.]$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000162406 8564_ $$s1993782$$uhttps://zaguan.unizar.es/record/162406/files/texto_completo.pdf$$yVersión publicada
000162406 8564_ $$s2938403$$uhttps://zaguan.unizar.es/record/162406/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000162406 909CO $$ooai:zaguan.unizar.es:162406$$particulos$$pdriver
000162406 951__ $$a2025-10-17-14:14:13
000162406 980__ $$aARTICLE