162406 20251017144601.0 doi 10.1002/chem.202501606 sideral 144995 ART-2025-144995 eng Demonti, Luca Platform Design Enabling Silver(III) Stabilization ─ The Uprise of Ag^IIICF₃ Chemistry? 2025 Access copy available to the general public Unrestricted Unlike its coinage metal counterparts, copper and gold, silver chemistry remains poorly developed and mostly restricted to the oxidation state +I, which embraces a large variety of coordination environments and types of ligand. Higher oxidation states, that is, +II and +III, are significantly less represented and predominantly adopt a square planar (SP‐4) geometry around the metal center. In particular, well‐defined d8 AgIII compounds are scarce, and include only a handful of examples exhibiting out‐of‐plane silver coordination. This Concept Article summarizes the strategies known to stabilize AgIII, as well as the unusual electronic structures (inverted ligand field) often found in these compounds. The intriguing case study of the expansion in the coordination number in AgIIICF3 compounds will be highlighted. info:eu-repo/grantAgreement/ES/DGA/E17-23R info:eu-repo/grantAgreement/ES/MICINN/PID2021-122869NB-I00 info:eu-repo/semantics/openAccess by https://creativecommons.org/licenses/by/4.0/deed.es info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Joven-Sancho, Daniel Universidad de Zaragoza (orcid)0000-0002-0204-7713 Baya, Miguel Universidad de Zaragoza (orcid)0000-0002-2492-625X Nebra, Noel 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 31, 44 (2025), e202501606 [13 pp.] Chemistry (Weinh.) Chemistry - A European Journal 0947-6539 1993782 http://zaguan.unizar.es/record/162406/files/texto_completo.pdf Versión publicada 2938403 http://zaguan.unizar.es/record/162406/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:162406 articulos driver 2025-10-17-14:14:13 ARTICLE