162997 20251009133842.0 doi 10.1039/d5tc02447a sideral 145517 ART-2025-145517 eng Bartolomé, Elena Magnetic and luminescent lanthanoid (Ln = Tb, Dy) 2D MOFs on functionalized silicon 2025 Access copy available to the general public Unrestricted The controlled deposition of organized molecular materials on technologically relevant substrates is crucial for the development of innovative magneto-optical devices. In this work, we report the growth of lanthanoid-based 2D metal–organic frameworks (MOFs) with formula unit [Ln(MeCOO)(PhCOO)2] (Ln = Dy, Tb) on Si(100) wafers functionalized by silanization. The thickness, morphology and composition of the grown material was assessed using a combination of ellipsometry, contact angle measurements, scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The on-surface grown terbium 2D MOFs exhibit green luminescence, like the bulk. Furthermore, chemisorbed Dy and Tb 2D MOFs retain a significant magnetic moment, as demonstrated by X-ray magnetic circular dichroism (XMCD) measurements conducted at the M4,5 edge of the two lanthanoids. Our work paves the way for the preparation of magneto-optical devices and organized arrays of single-molecule magnets (SMMs) and qubits on surfaces for high-density information storage and quantum computing applications. info:eu-repo/grantAgreement/ES/DGA/E12-23R info:eu-repo/grantAgreement/ES/MCIU/PGC2018-098630-B-I00 info:eu-repo/grantAgreement/ES/MICINN/PID2022-137764OB-I00 info:eu-repo/grantAgreement/ES/MICINN/PID2022-138492NB-I00 info:eu-repo/semantics/openAccess by-nc https://creativecommons.org/licenses/by-nc/4.0/deed.es info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Sevilla, Pablo Gabarró-Riera, Guillem Arauzo, Ana Universidad de Zaragoza (orcid)0000-0002-5999-341X Rubio Zuazo, Juan Sañudo, E. Carolina 2003 395 Universidad de Zaragoza Dpto. Física Materia Condensa. Área Física Materia Condensada (2025), [12 pp.] J. mater. chem. C JOURNAL OF MATERIALS CHEMISTRY C 2050-7526 2369999 http://zaguan.unizar.es/record/162997/files/texto_completo.pdf Versión publicada 2768540 http://zaguan.unizar.es/record/162997/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:162997 articulos driver 2025-10-09-13:25:57 ARTICLE