doi:10.1016/j.ica.2025.122948engKordestani, NazaninMartinez-Aguilera, AlvaroAbas, ElisaGrasa, LauraScalambra, FrancoRomerosa, AntonioSynthesis, characterizacion and study of novel heterobimetallic RAPTA-type Ru(II) complexesART-2025-145790The new monometallic RAPTA complex [RuCl2(η6-p-cym)(dmPTA-κP)](CF3SO3)2 (1) and novel heterobimetallic complexes [RuCl2(η6-p-cym)-μ-(dmoPTA)-(1κP:2κ2N,N′-M(L)Cl2)] (M = Cu (3); M = Cu, L = DMF (3·3DMF); M = Pd (4)) have been synthesized and characterized (dmPTA = N,N′-dimethyl-1,3,5-triaza-7-phosphaadamantane; dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane). The synthesized complexes have been fully characterized by elemental analysis and spectroscopic techniques. The crystal structure of the complexes 2, 3·3DMF and 4 were determined by single-crystal X-ray diffraction. The stability of complexes was studied in water and DMSO at room temperature and 37 °C. The anticancer activity against intestinal Caco-2/TC7 cells was studied.2025http://zaguan.unizar.es/record/16372910.1016/j.ica.2025.122948http://zaguan.unizar.es/record/163729oai:zaguan.unizar.es:163729INORGANICA CHIMICA ACTA 589 (2025), 122948 [9 pp.]by-nchttps://creativecommons.org/licenses/by-nc/4.0/deed.esinfo:eu-repo/semantics/openAccess