000163814 001__ 163814
000163814 005__ 20251204145008.0
000163814 0247_ $$2doi$$a10.1002/ejic.202500294
000163814 0248_ $$2sideral$$a145845
000163814 037__ $$aART-2025-145845
000163814 041__ $$aeng
000163814 100__ $$aPadilla, Marina$$uUniversidad de Zaragoza
000163814 245__ $$aInsights into the Base-Stabilized Silylene Nature of the Ir--Si Bond in Ir(III)–(κ2-NSi) Complexes with 2-Quinolone and 2-Pyridone Type Ligands
000163814 260__ $$c2025
000163814 5060_ $$aAccess copy available to the general public$$fUnrestricted
000163814 5203_ $$aA series of Ir–(κ2‐NSi) complexes with 2‐quinolone type ligands have been prepared and characterized to increase our scope of 16e unsaturated Ir–(κ2‐NSi) species to carry out a comprehensive study of the nature of the Ir--Si bond. Density functional theory calculations with natural bond orbital and quantum theory of atoms in molecules analyses of a range of Ir–silyl(ene) complexes allows the description of the Ir--Si bond of the examinated complexes as a polarized covalent interaction. The findings of this study also suggest that the most accurate description of this bond in the Ir–(κ2‐NSi) complexes is base‐stabilized silylene. Investigating the silicon environment has been the key for determining the nature of the Ir--Si bond. This insight also enables to elucidate the base‐stabilized TM–silylene character in other complexes.
000163814 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E42-23R$$9info:eu-repo/grantAgreement/EC/H2020/101034288/EU/International Fellowship Programme for Talent Attraction to the Campus of International Excellence Campus Iberus/IberusExperience$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 101034288-IberusExperience$$9info:eu-repo/grantAgreement/ES/MICINN/PID2021-126212OB-I00
000163814 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
000163814 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000163814 700__ $$0(orcid)0000-0002-1430-1440$$aBatuecas, María$$uUniversidad de Zaragoza
000163814 700__ $$0(orcid)0000-0002-7063-1292$$aGarcía-Orduña, Pilar
000163814 700__ $$0(orcid)0000-0001-7154-7239$$aOro, Luis A.$$uUniversidad de Zaragoza
000163814 700__ $$0(orcid)0000-0002-0497-1969$$aFernández-Alvarez, Francisco José$$uUniversidad de Zaragoza
000163814 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000163814 773__ $$g28, 27 (2025), e202500294 [12 pp.]$$pEur. j. inorg. chem.$$tEuropean Journal of Inorganic Chemistry$$x1434-1948
000163814 8564_ $$s1028247$$uhttps://zaguan.unizar.es/record/163814/files/texto_completo.pdf$$yVersión publicada
000163814 8564_ $$s2776577$$uhttps://zaguan.unizar.es/record/163814/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000163814 909CO $$ooai:zaguan.unizar.es:163814$$particulos$$pdriver
000163814 951__ $$a2025-12-04-14:45:27
000163814 980__ $$aARTICLE