000163900 001__ 163900
000163900 005__ 20251113160752.0
000163900 0247_ $$2doi$$a10.1016/j.ijadhadh.2012.07.003
000163900 0248_ $$2sideral$$a80611
000163900 037__ $$aART-2013-80611
000163900 041__ $$aeng
000163900 100__ $$0(orcid)0000-0003-2685-5739$$aNerin,C.$$uUniversidad de Zaragoza
000163900 245__ $$aDetermination of partition and diffusion coefficients of components of two rubber adhesives in different multilayer materials
000163900 260__ $$c2013
000163900 5060_ $$aAccess copy available to the general public$$fUnrestricted
000163900 5203_ $$aRubber adhesives both natural and synthetic are widely used in the manufacture of multilayer laminates, commonly used as food packaging. For this reason, it is very important to identify the compounds that could migrate from the laminate into the food. Twenty nine compounds were identified in two different rubber adhesives, some of them with high toxicity levels according to the theoretical model of Cramer such as benzene 4-cyanocyclohexene and benzene isothiocyanate. Partition of these compounds between the adhesive and different substrates and diffusion in both media were experimentally determined obtaining great variability of values depending on the properties of the compounds and the substrates used. Finally, only three compounds were found to migrate: benzene 4-cyanocyclohexene, butylated hydroxytoluene and 2-cyclopentyl-1.3.5-trimethylbenzene, with values of migration of 1.79, 22.9 μg/dm2 and 4.57 μg/dm2 respectively. These values were below the specific migration limits (SML) enforced by the legislation of the European Union (EU) and the values recommended by Cramer.
000163900 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
000163900 590__ $$a2.216$$b2013
000163900 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b65 / 246 = 0.264$$c2013$$dQ2$$eT1
000163900 591__ $$aENGINEERING, CHEMICAL$$b37 / 131 = 0.282$$c2013$$dQ2$$eT1
000163900 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000163900 700__ $$aGaspar,J.
000163900 700__ $$0(orcid)0000-0002-8765-4319$$aVera,P.$$uUniversidad de Zaragoza
000163900 700__ $$0(orcid)0000-0003-2638-9221$$aCanellas,E.
000163900 700__ $$0(orcid)0000-0002-0759-9170$$aAznar,M.$$uUniversidad de Zaragoza
000163900 700__ $$aMercea,P.
000163900 7102_ $$12009$$2750$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cÁrea Química Analítica
000163900 7102_ $$12009$$2X$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cProy. investigación HVA
000163900 773__ $$g40 (2013), 56-63$$pInt. j. adhes. adhes.$$tINTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES$$x0143-7496
000163900 8564_ $$s500293$$uhttps://zaguan.unizar.es/record/163900/files/texto_completo.pdf$$yPostprint
000163900 8564_ $$s1449723$$uhttps://zaguan.unizar.es/record/163900/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000163900 909CO $$ooai:zaguan.unizar.es:163900$$particulos$$pdriver
000163900 951__ $$a2025-11-13-14:57:27
000163900 980__ $$aARTICLE