000163948 001__ 163948
000163948 005__ 20251113160752.0
000163948 0247_ $$2doi$$a10.1002/ejic.202500315
000163948 0248_ $$2sideral$$a146109
000163948 037__ $$aART-2025-146109
000163948 041__ $$aeng
000163948 100__ $$0(orcid)0000-0003-2260-676X$$aPérez-Bitrián, Alberto
000163948 245__ $$aDifferentiating between F and OH Ligands in Homologous Gold(III) Complexes beyond X‐Ray Crystallography
000163948 260__ $$c2025
000163948 5060_ $$aAccess copy available to the general public$$fUnrestricted
000163948 5203_ $$aThe homologous fluoride and hydroxide complexes of gold(III) [PPh4][(CF3)3AuX] [X = F (1), OH (2)] have been structurally characterized by single-crystal X-ray diffraction methods. Both of them crystallize in the P21/n space group, yet they are not isomorphous. Despite the intrinsic difficulty to distinguish between F− and OH− by X-ray diffraction, the ability of the OH ligand in complex 2 to establish intramolecular OH…F hydrogen bonding with one of the CF3 groups in cis position enables a clear differentiation from the fluoride complex 1. Given the tendency of late-transition metal fluorides to undergo hydrolysis, much caution should be taken when ascribing the identity of a fluoride ligand by X-ray diffraction methods, especially where unusual geometries are implied.
000163948 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E17-23R$$9info:eu-repo/grantAgreement/ES/MICIU/PID2021-122869NB-I00$$9info:eu-repo/grantAgreement/ES/MICIU/PID2024-155563NB-I00
000163948 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
000163948 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000163948 700__ $$0(orcid)0000-0002-0204-7713$$aJoven-Sancho, Daniel$$uUniversidad de Zaragoza
000163948 700__ $$0(orcid)0000-0002-2492-625X$$aBaya, Miguel$$uUniversidad de Zaragoza
000163948 700__ $$aMartín, Antonio
000163948 700__ $$0(orcid)0000-0003-3514-2570$$aOrduna, Jesús
000163948 700__ $$0(orcid)0000-0001-9045-5102$$aMenjón, Babil
000163948 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000163948 773__ $$ge202500315 (2025), [10 pp.]$$pEur. j. inorg. chem.$$tEuropean Journal of Inorganic Chemistry$$x1434-1948
000163948 8564_ $$s1759805$$uhttps://zaguan.unizar.es/record/163948/files/texto_completo.pdf$$yVersión publicada
000163948 8564_ $$s2803446$$uhttps://zaguan.unizar.es/record/163948/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
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000163948 951__ $$a2025-11-13-14:58:23
000163948 980__ $$aARTICLE