000164117 001__ 164117
000164117 005__ 20251121161351.0
000164117 0247_ $$2doi$$a10.1002/zaac.202500150
000164117 0248_ $$2sideral$$a146258
000164117 037__ $$aART-2025-146258
000164117 041__ $$aeng
000164117 100__ $$0(orcid)0000-0003-2260-676X$$aPérez-Bitrián, Alberto
000164117 245__ $$aHeterobimetallic Pt(II) Complexes Supported by 1,8-Naphthyridine Ligands Confirm the Rotation of C6F5 Groups about the Pt−C Bond
000164117 260__ $$c2025
000164117 5060_ $$aAccess copy available to the general public$$fUnrestricted
000164117 5203_ $$aThe ligand 1,8-naphthyridine (napy) exhibits a rich coordination chemistry arising from the disposition of its two nitrogen atoms. In this work, the mononuclear platinum complex cis-[Pt(C6F5)2(napy)2] was synthesized and used to prepare other platinum complexes such as cis-[Pt(C6F5)Cl(napy)2]. More importantly, its suitability as precursor for the synthesis of other heterobimetallic donor–acceptor complexes of the type Pt → M (M = Ag, Cu) was explored. This way, complexes cis-[Pt(C6F5)2(μ-napy)2Ag(OClO3)] and cis-[Pt(C6F5)2(μ-napy)2Cu(NCMe)][PF6] were prepared, in which two napy ligands bridge both metal atoms. In the rare Pt → Cu donor–acceptor complex, the MeCN ligand was easily substituted by a chlorido ligand, resulting in cis-[Pt(C6F5)2(μ-napy)2CuCl] and [{Pt(C6F5)2(μ-napy)2Cu}2(μ-Cl)][PF6], depending on the stoichiometry. In all cases, the free rotation of the C6F5 ligands about the Pt−C bonds in solution at room temperature can be stopped at low temperature.
000164117 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E17-23R$$9info:eu-repo/grantAgreement/ES/MECD/FPU15-03940$$9info:eu-repo/grantAgreement/ES/MICIU/PID2021-122869NB-I00
000164117 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttps://creativecommons.org/licenses/by/4.0/deed.es
000164117 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000164117 700__ $$aMunárriz, Carmen$$uUniversidad de Zaragoza
000164117 700__ $$aRueda, Ángel J.
000164117 700__ $$0(orcid)0000-0002-4808-574X$$aMartín, Antonio
000164117 700__ $$0(orcid)0000-0003-0341-7699$$aCasas, José M.$$uUniversidad de Zaragoza
000164117 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000164117 773__ $$ge202500150 (2025), [10 pp.]$$pZ. anorg. allg. Chem.$$tZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE$$x0044-2313
000164117 8564_ $$s1375393$$uhttps://zaguan.unizar.es/record/164117/files/texto_completo.pdf$$yVersión publicada
000164117 8564_ $$s2992916$$uhttps://zaguan.unizar.es/record/164117/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000164117 909CO $$ooai:zaguan.unizar.es:164117$$particulos$$pdriver
000164117 951__ $$a2025-11-21-14:26:51
000164117 980__ $$aARTICLE