000165304 001__ 165304 000165304 005__ 20251219174252.0 000165304 0247_ $$2doi$$a10.1002/anie.202202241 000165304 0248_ $$2sideral$$a146981 000165304 037__ $$aART-2022-146981 000165304 041__ $$aeng 000165304 100__ $$0(orcid)0000-0002-1430-1440$$aBatuecas, María$$uUniversidad de Zaragoza 000165304 245__ $$aFunctionalization and Hydrogenation of Carbon Chains Derived from CO** 000165304 260__ $$c2022 000165304 5060_ $$aAccess copy available to the general public$$fUnrestricted 000165304 5203_ $$aSelective reactions that combine H2, CO and organic electrophiles (aldehyde, ketones, isocyanide) to form hydrogenated C3 and C4 carbon chains are reported. These reactions proceed by CO homologation mediated by [W(CO)6] and an aluminum(I) reductant, followed by functionalization and hydrogenation of the chain ends. A combination of kinetics (rates, KIEs) and DFT calculations has been used to gain insight into a key step which involves hydrogenation of a metal-locarbene intermediate. These findings expand the extremely small scope of systems that combine H2 and CO to make well-defined products with complete control over chain length and functionality 000165304 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttps://creativecommons.org/licenses/by/4.0/deed.es 000165304 590__ $$a16.6$$b2022 000165304 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b13 / 178 = 0.073$$c2022$$dQ1$$eT1 000165304 592__ $$a5.573$$b2022 000165304 593__ $$aChemistry (miscellaneous)$$c2022$$dQ1 000165304 593__ $$aCatalysis$$c2022$$dQ1 000165304 594__ $$a26.3$$b2022 000165304 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000165304 700__ $$aKong, Richard Y. 000165304 700__ $$aWhite, Andrew J. P. 000165304 700__ $$aCrimmin, Mark R. 000165304 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica 000165304 773__ $$g61, 20 (2022), e202202241 [5 pp.]$$pAngew. Chem. (Int. ed.)$$tAngewandte Chemie (International ed.)$$x1433-7851 000165304 8564_ $$s1310853$$uhttps://zaguan.unizar.es/record/165304/files/texto_completo.pdf$$yVersión publicada 000165304 8564_ $$s2798262$$uhttps://zaguan.unizar.es/record/165304/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000165304 909CO $$ooai:zaguan.unizar.es:165304$$particulos$$pdriver 000165304 951__ $$a2025-12-19-14:44:46 000165304 980__ $$aARTICLE