165328 20260107201858.0 doi 10.1016/j.dyepig.2015.02.026 sideral 97720 ART-2015-97720 eng González-Lainez, M. Universidad de Zaragoza (orcid)0000-0001-7341-0033 Using functionalized nonlinear optical chromophores to prepare NLO-active polycarbonate films 2015 Novel functionalized second order nonlinear optical (NLO) chromophores have been prepared with functionalized aniline as electron donor, thiophene or isophorone as a p-spacer and 1,3-diethyl-2- thiobarbituric acid as electron acceptor. The films prepared from dyes with alkylsilyl bulky groups gave better performance than the corresponding non functionalized chromophores due to the reduction of the intermolecular electrostatic interactions. The incorporation of chromophores 4 and 10 in a poly- carbonate matrix allowed the preparation of good optical-quality films. Nonlinear coefficients d33 and d31 as high as 17 and 5.6 pm V-1, respectively, were obtained. Moreover, the temporal stability of these host- guest films was confirmed up to eight months (>80%). Access copy available to the general public Unrestricted info:eu-repo/grantAgreement/ES/DGA/E04 info:eu-repo/grantAgreement/ES/DGA/E39 info:eu-repo/grantAgreement/ES/MINECO/CTQ2011-22727 info:eu-repo/grantAgreement/ES/MINECO/MAT2011-27978-C02-02 info:eu-repo/semantics/openAccess by-nc-nd https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es 4.055 2015 CHEMISTRY, APPLIED 6 / 72 = 0.083 2015 Q1 T1 MATERIALS SCIENCE, TEXTILES 1 / 23 = 0.043 2015 Q1 T1 ENGINEERING, CHEMICAL 17 / 135 = 0.126 2015 Q1 T1 0.957 2015 Process Chemistry and Technology 2015 Q1 Chemical Engineering (miscellaneous) 2015 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Jiménez-Ruiz, M.T. Martínez de Baroja, N. Garín, J. Universidad de Zaragoza (orcid)0000-0001-8265-8970 Orduna, J. Universidad de Zaragoza (orcid)0000-0003-3514-2570 Villacampa, B. Universidad de Zaragoza (orcid)0000-0001-9814-0834 Blesa, M.J. Universidad de Zaragoza (orcid)0000-0001-7193-1732 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 2013 765 Universidad de Zaragoza Dpto. Química Orgánica Área Química Orgánica 2003 395 Universidad de Zaragoza Dpto. Física Materia Condensa. Área Física Materia Condensada 119 (2015), 30-40 Dyes pigm. Dyes and Pigments 0143-7208 2859749 http://zaguan.unizar.es/record/165328/files/texto_completo.pdf Postprint 911734 http://zaguan.unizar.es/record/165328/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:165328 articulos driver 2026-01-07-18:52:29 ARTICLE