000165409 001__ 165409
000165409 005__ 20260108143204.0
000165409 0247_ $$2doi$$a10.1016/j.cattod.2020.03.014
000165409 0248_ $$2sideral$$a117120
000165409 037__ $$aART-2020-117120
000165409 041__ $$aeng
000165409 100__ $$aRaso, R.
000165409 245__ $$aZeolite membranes: Comparison in the separation of H2O/H2/CO2 mixtures and test of a reactor for CO2 hydrogenation to methanol
000165409 260__ $$c2020
000165409 5060_ $$aAccess copy available to the general public$$fUnrestricted
000165409 5203_ $$aA zeolite membrane reactor can be employed for hydrogenation of CO2 to methanol. The removal of water from the reaction environment would increase the reaction rate and the achievable conversion. The separation of water from mixtures containing CO2, hydrogen and water at suitable temperatures for this reaction was tested with several zeolite membranes (zeolite A, mordenite, zeolite T, chabazite and Ti-Chabazite). Zeolite A provided the best H2O/H2 separation factor. Preliminary experiments comparing a traditional reactor and the combination of a traditional reactor with a membrane reactor show that the yield of methanol was improved, in one case being higher than the limit corresponding to the thermodynamic equilibrium in a conventional reactor.
000165409 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-76533-R
000165409 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
000165409 590__ $$a6.766$$b2020
000165409 591__ $$aCHEMISTRY, APPLIED$$b10 / 74 = 0.135$$c2020$$dQ1$$eT1
000165409 591__ $$aENGINEERING, CHEMICAL$$b19 / 143 = 0.133$$c2020$$dQ1$$eT1
000165409 591__ $$aCHEMISTRY, PHYSICAL$$b36 / 162 = 0.222$$c2020$$dQ1$$eT1
000165409 592__ $$a1.397$$b2020
000165409 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1
000165409 593__ $$aCatalysis$$c2020$$dQ1
000165409 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000165409 700__ $$aTovar, M.
000165409 700__ $$0(orcid)0000-0002-7488-6196$$aLasobras, J.
000165409 700__ $$0(orcid)0000-0003-1940-9597$$aHerguido, J.$$uUniversidad de Zaragoza
000165409 700__ $$aKumakiri, I.
000165409 700__ $$aAraki, S.
000165409 700__ $$0(orcid)0000-0002-2494-102X$$aMenéndez, M.$$uUniversidad de Zaragoza
000165409 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000165409 773__ $$g364 (2020), 270-275$$pCatal. today$$tCatalysis Today$$x0920-5861
000165409 8564_ $$s611179$$uhttps://zaguan.unizar.es/record/165409/files/texto_completo.pdf$$yPostprint
000165409 8564_ $$s422952$$uhttps://zaguan.unizar.es/record/165409/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000165409 909CO $$ooai:zaguan.unizar.es:165409$$particulos$$pdriver
000165409 951__ $$a2026-01-08-14:10:05
000165409 980__ $$aARTICLE