167901 20260128154426.0 doi 10.1002/smll.202508348 sideral 147333 ART-2025-147333 eng Quirós-Ovies, Ramiro An à la Carte Synthesis Approach for Chemically Linking Au, Pt, and Pd Nanoparticles to Few‐Layer 2H‐MoS 2025 The combination of 2D materials and metallic nanoparticles (NPs) enables the creation of hybrid systems with enhanced properties, such as improved light absorption via plasmon resonance or the introduction of active catalytic sites. However, effectively interfacing 2D materials with NPs remains challenging. This work presents a novel and efficient à la carte synthesis approach that enables the tailored chemical linkage of noble metal NPs—gold (Au), platinum (Pt), and palladium (Pd)— to ultrathin 2H-MoS2 sheets using orthogonal maleimide-based linkers. Specifically, alkyne-, carboxylic acid-, and phenyl bromide-terminated maleimides are employed to anchor Au, Pt, and Pd NPs, respectively. This modular strategy allows precise control over the surface chemistry, leading to uniform decoration with sub-2 nm NPs and robust attachment to the MoS2 substrate. This chemical linkage is expected to enhance the interaction between the MoS2 and the NPs while also improving the mechanical stability of the hybrid material. These combined effects make the system particularly promising for applications requiring both strong interfacial coupling and durability, such as electrocatalysis, sensing, and flexible electronic devices. info:eu-repo/grantAgreement/ES/MICINN/PID2021-127847OB-I00 info:eu-repo/grantAgreement/ES/MICINN/PID2024-1603390B-100 info:eu-repo/grantAgreement/ES/MICIU/CEX2023-001286-S info:eu-repo/semantics/closedAccess All rights reserved http://www.europeana.eu/rights/rr-f/ info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Bonet, Javier (orcid)0000-0002-1791-0188 Pérez, Emilio M. Santamaría, Jesús Universidad de Zaragoza (orcid)0000-0002-8701-9745 Sebastián, Víctor Universidad de Zaragoza (orcid)0000-0002-6873-5244 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 21, 51 (2025), e08348 [12 pp.] Small Small 1613-6810 2298741 http://zaguan.unizar.es/record/167901/files/texto_completo.pdf Versión publicada info:eu-repo/date/embargoEnd/2026-11-19 2635998 http://zaguan.unizar.es/record/167901/files/texto_completo.jpg?subformat=icon icon Versión publicada info:eu-repo/date/embargoEnd/2026-11-19 oai:zaguan.unizar.es:167901 articulos driver 2026-01-28-15:42:25 ARTICLE