000168205 001__ 168205
000168205 005__ 20260128162436.0
000168205 0247_ $$2doi$$a10.1021/acs.energyfuels.9b01760
000168205 0248_ $$2sideral$$a114829
000168205 037__ $$aART-2019-114829
000168205 041__ $$aeng
000168205 100__ $$0(orcid)0000-0002-4674-3614$$aAlexandrino, Katiuska
000168205 245__ $$aReactivity and Physicochemical Properties of the Soot Produced in the Pyrolysis of 2, 5-Dimethylfuran and 2-Methylfuran
000168205 260__ $$c2019
000168205 5060_ $$aAccess copy available to the general public$$fUnrestricted
000168205 5203_ $$aAlkylated furan derivatives, such as 2, 5-dimethylfuran (2, 5-DMF) and 2-methylfuran (2-MF), have shown, at laboratory scale, a relatively high tendency to form soot. However, soot emissions from diesel engines are lower when diesel/2, 5-DMF and diesel/2-MF blends are used. This could indicate that the soot produced in the conversion of these compounds has high reactivity toward some gases present within the combustion chamber, reducing soot emissions in the exhaust gas. In this context, a study on the reactivity and the characterization of the soot generated in the pyrolysis of 2, 5-DMF and 2-MF, under different experimental conditions, was performed in an effort to increase the understanding of the reactivity and physicochemical properties of the soot originating in the conversion of these furan derivatives. The soot samples analyzed were obtained in previous works using different concentrations of the alkylated furan derivatives (5000, 7500, and 15â»000 ppm of 2, 5-DMF, and 9000 and 18â»000 ppm of 2-MF) and at different temperatures (1275, 1375, and 1475 K). The reactivity experiments were performed at 1275 K with 500 ppm of O2 and 2000 ppm of NO in a tubular quartz flow reactor. Different instrumental analysis techniques were employed to characterize the soot samples and to try to link the soot reactivity with its physicochemical properties. The dependence of soot reactivity and properties with soot formation conditions, namely, temperature and inlet fuel concentration, is studied.
000168205 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FEDER/T22-17R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-65226
000168205 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000168205 590__ $$a3.421$$b2019
000168205 591__ $$aENGINEERING, CHEMICAL$$b50 / 142 = 0.352$$c2019$$dQ2$$eT2
000168205 591__ $$aENERGY & FUELS$$b55 / 112 = 0.491$$c2019$$dQ2$$eT2
000168205 592__ $$a1.044$$b2019
000168205 593__ $$aEnergy Engineering and Power Technology$$c2019$$dQ1
000168205 593__ $$aFuel Technology$$c2019$$dQ1
000168205 593__ $$aChemical Engineering (miscellaneous)$$c2019$$dQ1
000168205 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000168205 700__ $$0(orcid)0000-0001-5426-6486$$aMillera, Ángela$$uUniversidad de Zaragoza
000168205 700__ $$0(orcid)0000-0002-5420-0943$$aBilbao, Rafael$$uUniversidad de Zaragoza
000168205 700__ $$0(orcid)0000-0003-4679-5761$$aAlzueta, María U.$$uUniversidad de Zaragoza
000168205 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000168205 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente
000168205 773__ $$g33, 10 (2019), 9851-9858$$pEnergy fuels$$tEnergy and Fuels$$x0887-0624
000168205 8564_ $$s1017748$$uhttps://zaguan.unizar.es/record/168205/files/texto_completo.pdf$$yPostprint
000168205 8564_ $$s613757$$uhttps://zaguan.unizar.es/record/168205/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000168205 909CO $$ooai:zaguan.unizar.es:168205$$particulos$$pdriver
000168205 951__ $$a2026-01-28-15:37:48
000168205 980__ $$aARTICLE