000168240 001__ 168240
000168240 005__ 20260219141445.0
000168240 0247_ $$2doi$$a10.1039/c7cc07712b
000168240 0248_ $$2sideral$$a104689
000168240 037__ $$aART-2017-104689
000168240 041__ $$aeng
000168240 100__ $$0(orcid)0000-0002-5881-9698$$aAra, I.$$uUniversidad de Zaragoza
000168240 245__ $$aA route to small clusters: A twisted half-hexagram-shaped M4(OH)4 cluster and its capacity for hosting closed-shell metals
000168240 260__ $$c2017
000168240 5060_ $$aAccess copy available to the general public$$fUnrestricted
000168240 5203_ $$aBy combining different oxidation states, coordination indices and bridging systems, it has been possible to obtain the structurally novel M4(OH)4 cluster core (M = transition metal) found in the organometallic compound (NBu4)2[PtIVPtII3(C6Cl5)8(µ2-OH)2(µ3-OH)2] (1). The cluster is formed by two (µ3-OH) and two (µ2-OH) units that bond platinum atoms in different oxidation states. The cluster core geometry can best be described as a half-hexagram. Compound 1 is an excellent precursor for preparing heterometallic clusters since it can host d10 or s2 Lewis-acid metal centers through Pt¿M dative bonds, as demonstrated by its reaction with Ag(i) to produce the heterometallic [Ag2PtIVPtII3(C6Cl5)8(µ2-OH)2(µ3-OH)2] (2), which has four unbridged Pt-Ag bonds.
000168240 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E21$$9info:eu-repo/grantAgreement/ES/MCIU/MAT2015-68200-C2-1-P$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67461-P
000168240 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000168240 590__ $$a6.29$$b2017
000168240 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b28 / 169 = 0.166$$c2017$$dQ1$$eT1
000168240 592__ $$a2.555$$b2017
000168240 593__ $$aCatalysis$$c2017$$dQ1
000168240 593__ $$aCeramics and Composites$$c2017$$dQ1
000168240 593__ $$aChemistry (miscellaneous)$$c2017$$dQ1
000168240 593__ $$aSurfaces, Coatings and Films$$c2017$$dQ1
000168240 593__ $$aMaterials Chemistry$$c2017$$dQ1
000168240 593__ $$aMetals and Alloys$$c2017$$dQ1
000168240 593__ $$aElectronic, Optical and Magnetic Materials$$c2017$$dQ1
000168240 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000168240 700__ $$0(orcid)0000-0001-7901-1420$$aGarciá-Monforte, M.A.$$uUniversidad de Zaragoza
000168240 700__ $$aGonzález, R.
000168240 700__ $$0(orcid)0000-0002-0444-996X$$aFalvello, L.R.$$uUniversidad de Zaragoza
000168240 700__ $$aTomás, M.
000168240 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000168240 7102_ $$12010$$2X$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Técnica. Lab. y Talleres
000168240 773__ $$g53, 98 (2017), 13121-13124$$pChem. commun.$$tChemical Communications$$x1359-7345
000168240 8564_ $$s596143$$uhttps://zaguan.unizar.es/record/168240/files/texto_completo.pdf$$yPostprint
000168240 8564_ $$s2589723$$uhttps://zaguan.unizar.es/record/168240/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000168240 909CO $$ooai:zaguan.unizar.es:168240$$particulos$$pdriver
000168240 951__ $$a2026-02-19-14:14:02
000168240 980__ $$aARTICLE