000168564 001__ 168564
000168564 005__ 20260212204406.0
000168564 0248_ $$2sideral$$a148021
000168564 037__ $$aART-2002-148021
000168564 041__ $$aeng
000168564 100__ $$0(orcid)0000-0002-8648-2586$$aBlanco Ortiz, María del Carmen
000168564 245__ $$aA pentanuclear mixed gold(III)-silver(I) phosphide with an unusual T-frame 3-Cl bridge.
000168564 260__ $$c2002
000168564 5060_ $$aAccess copy available to the general public$$fUnrestricted
000168564 5203_ $$aThe reaction of the mixed gold(III)-silver(I) diphenylphosphide complex [Au(C6F5)2(µPPh2)2Ag]2 (1) with an equimolecular amount of [AgCl(PPh3)2] leads to the formal insertion of the latter into 1, affording the pentanuclear derivative [{Au(C6F5)2{(µ-PPh2)AgPPh3}(µPPh2)}2(µ-Ag)(µ3-Cl)] (2). Surprisingly, complex 2 is also obtained by treatment of [Au(C6F5)2- (PPh2H)2]ClO4 with [Ag(TfO)(PPh3)] (TfO ) trifluoromethanesulfonate) and AgTfO (2:2:1) in the presence of PPN(acac) (PPN ) [N(PPh3)2]+, acac ) acetylacetonate) and PPNCl. The crystal structure of 2 has been determined by X-ray diffraction studies, and it displays an unusual, perfectly planar T-frame µ3-Cl atom acting as a bridge between the three silver atoms.
000168564 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000168564 590__ $$a3.215$$b2002
000168564 591__ $$aCHEMISTRY, ORGANIC$$b7 / 52 = 0.135$$c2002$$dQ1$$eT1
000168564 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b8 / 44 = 0.182$$c2002$$dQ1$$eT1
000168564 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000168564 700__ $$aFernández, E.J.
000168564 700__ $$aOlmo, M.E.
000168564 700__ $$0(orcid)0000-0001-9522-5840$$aCrespo, Olga$$uUniversidad de Zaragoza
000168564 700__ $$0(orcid)0000-0003-1984-7538$$aLaguna, Antonio$$uUniversidad de Zaragoza
000168564 700__ $$aJones, Peter G.
000168564 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000168564 773__ $$g21 (2002), 2426-2429$$pOrganometallics$$tOrganometallics$$x0276-7333
000168564 8564_ $$s253316$$uhttps://zaguan.unizar.es/record/168564/files/texto_completo.pdf$$yPostprint
000168564 8564_ $$s1153244$$uhttps://zaguan.unizar.es/record/168564/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000168564 909CO $$ooai:zaguan.unizar.es:168564$$particulos$$pdriver
000168564 951__ $$a2026-02-12-20:41:33
000168564 980__ $$aARTICLE