168564 20260212204406.0 sideral 148021 ART-2002-148021 eng Blanco Ortiz, María del Carmen (orcid)0000-0002-8648-2586 A pentanuclear mixed gold(III)-silver(I) phosphide with an unusual T-frame 3-Cl bridge. 2002 Access copy available to the general public Unrestricted The reaction of the mixed gold(III)-silver(I) diphenylphosphide complex [Au(C6F5)2(µPPh2)2Ag]2 (1) with an equimolecular amount of [AgCl(PPh3)2] leads to the formal insertion of the latter into 1, affording the pentanuclear derivative [{Au(C6F5)2{(µ-PPh2)AgPPh3}(µPPh2)}2(µ-Ag)(µ3-Cl)] (2). Surprisingly, complex 2 is also obtained by treatment of [Au(C6F5)2- (PPh2H)2]ClO4 with [Ag(TfO)(PPh3)] (TfO ) trifluoromethanesulfonate) and AgTfO (2:2:1) in the presence of PPN(acac) (PPN ) [N(PPh3)2]+, acac ) acetylacetonate) and PPNCl. The crystal structure of 2 has been determined by X-ray diffraction studies, and it displays an unusual, perfectly planar T-frame µ3-Cl atom acting as a bridge between the three silver atoms. info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 3.215 2002 CHEMISTRY, ORGANIC 7 / 52 = 0.135 2002 Q1 T1 CHEMISTRY, INORGANIC & NUCLEAR 8 / 44 = 0.182 2002 Q1 T1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Fernández, E.J. Olmo, M.E. Crespo, Olga Universidad de Zaragoza (orcid)0000-0001-9522-5840 Laguna, Antonio Universidad de Zaragoza (orcid)0000-0003-1984-7538 Jones, Peter G. 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 21 (2002), 2426-2429 Organometallics Organometallics 0276-7333 253316 http://zaguan.unizar.es/record/168564/files/texto_completo.pdf Postprint 1153244 http://zaguan.unizar.es/record/168564/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:168564 articulos driver 2026-02-12-20:41:33 ARTICLE