000168602 001__ 168602
000168602 005__ 20260211123813.0
000168602 0248_ $$2sideral$$a50168
000168602 037__ $$aART-2000-50168
000168602 041__ $$aeng
000168602 100__ $$0(orcid)0000-0002-8648-2586$$aBlanco, M. C
000168602 245__ $$aHeteropolynuclear phosphide complexes: phosphorus as unique atom bridging coinage metal centres.
000168602 260__ $$c2000
000168602 5203_ $$aIn this paper we describe the synthesis and reactivity of the diphenylphosphine derivatives [Au(C6F5)(PPh2H)] and trans-[Au(C6F5)2(PPh2H)2]ClO4. Reactions of the latter or the neutral [Au(C6F5)3(PPh2H)] with the appropriate Group 11 metal reagents (M=Au, Ag, Cu) in the presence of acetylacetonate afford a series of novel AuIII-M phosphido-bridged complexes, which have been scarcely represented to date. The crystal structure of the tetranuclear [{Au(C6F5)2(μ-PPh2)2Ag}2] and the dinuclear [Au(C6F5)3(μ-PPh2)M(PPh3)] (M=Au, Ag) complexes were established by X-ray diffraction methods. The synthesis and deprotonating activity of the anionic gold(III) complex PPN[Au(C6F5)3(acac)] (PNN=[N(PPh3)2]+) was studied.
000168602 540__ $$9info:eu-repo/semantics/closedAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000168602 590__ $$a4.698$$b2000
000168602 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b10 / 118 = 0.085$$c2000$$dQ1$$eT1
000168602 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000168602 700__ $$aFernandez, E. J
000168602 700__ $$aLopez De Luzuriaga, J. M
000168602 700__ $$aOlmos, M. E
000168602 700__ $$0(orcid)0000-0001-9522-5840$$aCrespo, O.$$uUniversidad de Zaragoza
000168602 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M. C
000168602 700__ $$0(orcid)0000-0003-1984-7538$$aLaguna, A.$$uUniversidad de Zaragoza
000168602 700__ $$aJones, P. G
000168602 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000168602 773__ $$g6, 22 (2000), 4116-23$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000168602 8564_ $$s170247$$uhttps://zaguan.unizar.es/record/168602/files/texto_completo.pdf$$yVersión publicada
000168602 8564_ $$s2424727$$uhttps://zaguan.unizar.es/record/168602/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000168602 909CO $$ooai:zaguan.unizar.es:168602$$particulos$$pdriver
000168602 951__ $$a2026-02-11-10:28:04
000168602 980__ $$aARTICLE