168602 20260211123813.0 sideral 50168 ART-2000-50168 eng Blanco, M. C (orcid)0000-0002-8648-2586 Heteropolynuclear phosphide complexes: phosphorus as unique atom bridging coinage metal centres. 2000 In this paper we describe the synthesis and reactivity of the diphenylphosphine derivatives [Au(C6F5)(PPh2H)] and trans-[Au(C6F5)2(PPh2H)2]ClO4. Reactions of the latter or the neutral [Au(C6F5)3(PPh2H)] with the appropriate Group 11 metal reagents (M=Au, Ag, Cu) in the presence of acetylacetonate afford a series of novel AuIII-M phosphido-bridged complexes, which have been scarcely represented to date. The crystal structure of the tetranuclear [{Au(C6F5)2(μ-PPh2)2Ag}2] and the dinuclear [Au(C6F5)3(μ-PPh2)M(PPh3)] (M=Au, Ag) complexes were established by X-ray diffraction methods. The synthesis and deprotonating activity of the anionic gold(III) complex PPN[Au(C6F5)3(acac)] (PNN=[N(PPh3)2]+) was studied. info:eu-repo/semantics/closedAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 4.698 2000 CHEMISTRY, MULTIDISCIPLINARY 10 / 118 = 0.085 2000 Q1 T1 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Fernandez, E. J Lopez De Luzuriaga, J. M Olmos, M. E Crespo, O. Universidad de Zaragoza (orcid)0000-0001-9522-5840 Gimeno, M. C (orcid)0000-0003-0553-0695 Laguna, A. Universidad de Zaragoza (orcid)0000-0003-1984-7538 Jones, P. G 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 6, 22 (2000), 4116-23 Chemistry (Weinh.) Chemistry - A European Journal 0947-6539 170247 http://zaguan.unizar.es/record/168602/files/texto_completo.pdf Versión publicada 2424727 http://zaguan.unizar.es/record/168602/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:168602 articulos driver 2026-02-11-10:28:04 ARTICLE