000168659 001__ 168659
000168659 005__ 20260212205631.0
000168659 0247_ $$2doi$$a10.1021/om200397t
000168659 0248_ $$2sideral$$a76493
000168659 037__ $$aART-2012-76493
000168659 041__ $$aeng
000168659 100__ $$0(orcid)0000-0002-8648-2586$$aBlanco, M. Carmen
000168659 245__ $$aLuminescent Homo- and Heteropolynuclear Gold Complexes Stabilized by a Unique Acetylide Fragment
000168659 260__ $$c2012
000168659 5060_ $$aAccess copy available to the general public$$fUnrestricted
000168659 5203_ $$aIn this paper we describe the reactivity of the gold acetylide derivatives [Au(C≡CR)(PPh3)] (R = Ph, 2-py). Reactions of these complexes with fragments of the type [M(PPh3)2]+ (M = Au, Ag, Cu) afford a series of novel discrete molecules stabilized not only by interactions with the triple bond but also by the formation of strong metal–gold interactions. The crystal structures of the gold–gold and gold–silver species confirm their similar behavior, while X-ray diffraction establishes a different arrangement for the copper complex with pyridine acetylide as a consequence of the coordination of this metal center to the nitrogen atom of pyridine and to the carbons of the alkyne. The luminescent properties of the complexes were also studied.
000168659 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E77$$9info:eu-repo/grantAgreement/ES/MICINN/CTQ2010-20500
000168659 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000168659 590__ $$a4.145$$b2012
000168659 591__ $$aCHEMISTRY, ORGANIC$$b11 / 57 = 0.193$$c2012$$dQ1$$eT1
000168659 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b6 / 44 = 0.136$$c2012$$dQ1$$eT1
000168659 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000168659 700__ $$aCámara, Jéssica$$uUniversidad de Zaragoza
000168659 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M. Concepción$$uUniversidad de Zaragoza
000168659 700__ $$aJones, Peter G.
000168659 700__ $$0(orcid)0000-0003-1984-7538$$aLaguna, Antonio$$uUniversidad de Zaragoza
000168659 700__ $$aLópez-de-Luzuriaga, José M.
000168659 700__ $$aOlmos, M. Elena
000168659 700__ $$0(orcid)0000-0002-3978-1145$$aVillacampa, M. Dolores$$uUniversidad de Zaragoza
000168659 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000168659 773__ $$g31, 7 (2012), 2597-2605$$pOrganometallics$$tOrganometallics$$x0276-7333
000168659 8564_ $$s748044$$uhttps://zaguan.unizar.es/record/168659/files/texto_completo.pdf$$yPostprint
000168659 8564_ $$s1064641$$uhttps://zaguan.unizar.es/record/168659/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000168659 909CO $$ooai:zaguan.unizar.es:168659$$particulos$$pdriver
000168659 951__ $$a2026-02-12-20:38:56
000168659 980__ $$aARTICLE