Repositorio Institucional de Documentos

000168719 001__ 168719
000168719 005__ 20260217214838.0
000168719 0247_ $$2doi$$a10.1039/C2DT32606J
000168719 0248_ $$2sideral$$a148119
000168719 037__ $$aART-2012-148119
000168719 041__ $$aeng
000168719 100__ $$0(orcid)0000-0001-8977-6734$$aBolaño, Tamara$$uUniversidad de Zaragoza
000168719 245__ $$aDirect coupling of nitriles and aniline to form the triazapentadiene species Rh<sup>III</sup>{NHC(R)N(Ph)C(R)NH}
000168719 260__ $$c2012
000168719 5203_ $$aThe facile and high-yield reaction between aniline and cis-positioned nitriles of [(tbpy)2Rh(NCR)2][OTf]3 [R = Me (2), Ph (3); tbpy = 4,4′-di-tert-butyl-2,2′-bipyridine; OTf = CF3SO3−] produces the RhIII-triazapentadiene species [(tbpy)2[upper bond 1 start]Rh{NH[double bond, length as m-dash]C(R)N(Ph)C(R)[double bond, length as m-dash]N[upper bond 1 end]H}][OTf]3 [R = Me (4), Ph (5)]. It represents the first example of direct coupling between two RCN ligands and a primary amine to form this type of metallacycle. X-ray structures of 2 and 4 are reported.
000168719 540__ $$9info:eu-repo/semantics/closedAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000168719 590__ $$a3.806$$b2012
000168719 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b8 / 44 = 0.182$$c2012$$dQ1$$eT1
000168719 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000168719 700__ $$aBrent Gunnoe, T.
000168719 700__ $$aSabat, Michal
000168719 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000168719 773__ $$g42, 2 (2012), 347-350$$pDalton Trans.$$tDalton Transactions$$x1477-9226
000168719 8564_ $$s404929$$uhttps://zaguan.unizar.es/record/168719/files/texto_completo.pdf$$yVersión publicada
000168719 8564_ $$s2961434$$uhttps://zaguan.unizar.es/record/168719/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000168719 909CO $$ooai:zaguan.unizar.es:168719$$particulos$$pdriver
000168719 951__ $$a2026-02-17-20:14:11
000168719 980__ $$aARTICLE