000168753 001__ 168753
000168753 005__ 20260217214838.0
000168753 0247_ $$2doi$$a10.1002/ejic.202500598
000168753 0248_ $$2sideral$$a148175
000168753 037__ $$aART-2026-148175
000168753 041__ $$aeng
000168753 100__ $$aEspañol-Sánchez, Belinda$$uUniversidad de Zaragoza
000168753 245__ $$aDinuclear Rhodium(I)–N-Heterocyclic Carbene Complexes as Alkyne Hydropyridonation Catalysts
000168753 260__ $$c2026
000168753 5060_ $$aAccess copy available to the general public$$fUnrestricted
000168753 5203_ $$aA series of new RhI–N-Heterocyclic carbene dinuclear complexes of type [Rh(µ-Cl)(η2-coe)(NHC)]2, containing IPrBIAN, IPrCl, and IPr* ligands, has been prepared. The crystal structure of the IPrCl functionalized rhodium–dinuclear complex reveals an intermolecular Cl···Cl halogen bond. The chlorido-bridges can be cleaved by pyridine to afford the corresponding mononuclear derivatives RhCl(η2-coe)(NHC)(py). These complexes are efficient alkyne hydropyridonation catalysts, with the IMes complex exhibiting the highest reactivity within the series. © 2026 The Author(s). European Journal of Inorganic Chemistry published by Wiley-VCH GmbH.
000168753 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E42-23R$$9info:eu-repo/grantAgreement/ES/MICINN/PID2022-137208NB-I00$$9info:eu-repo/grantAgreement/ES/MICIU/AEI/10.13039/501100011033
000168753 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
000168753 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000168753 700__ $$aKaratas, Mert Olgun
000168753 700__ $$aDi Giuseppe, Andrea
000168753 700__ $$aTogaev, Ulugbek
000168753 700__ $$aPassarelli, Vincenzo
000168753 700__ $$aOro, Luis A.
000168753 700__ $$aPérez-Torrente, Jesús J.
000168753 700__ $$aCastarlenas, Ricardo
000168753 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000168753 773__ $$g(2026), e202500598 [12 pp.]$$pEur. j. inorg. chem.$$tEuropean Journal of Inorganic Chemistry$$x1434-1948
000168753 8564_ $$s1166418$$uhttps://zaguan.unizar.es/record/168753/files/texto_completo.pdf$$yVersión publicada
000168753 8564_ $$s2606331$$uhttps://zaguan.unizar.es/record/168753/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000168753 909CO $$ooai:zaguan.unizar.es:168753$$particulos$$pdriver
000168753 951__ $$a2026-02-17-20:14:56
000168753 980__ $$aARTICLE